(a) Interpretation: The curved-arrow mechanism for the hydrolysis of the N -methylbenzamide in acidic solution is to be stated. Concept introduction: The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 1

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 3

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 4

Question

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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Answer 5

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 6

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 7

Chapter 21, Problem 21.10P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in basic solution is to be stated.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down from one bond using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains the curved-arrow mechanism for the hydrolysis of the N-methylbenzamide in acidic solution.

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Chapter 21 Solutions