(a) Interpretation: The major product of the reaction between propionyl chloride and H 2 O is to be predicated. Concept introduction: Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is RCOCl . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Question

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Answer 1

Question

Chapter 21, Problem 21.33AP

Interpretation Introduction

(a)

Interpretation:

The major product of the reaction between propionyl chloride and $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 1

Explanation of Solution

Propionyl chloride undergoes hydrolysis reaction to from propionic acid. The water molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form propionic acid.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 2

Figure 1

Conclusion

The major product of the reaction between propionyl chloride and $H2O$ is in Figure 1.

Interpretation Introduction

(b)

Interpretation:

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 3

Explanation of Solution

Propionyl chloride is a acyl chloride. It has a electrophilic carbonyl carbonyl carbon atom. The ethanethiol molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 4

Figure 2

Conclusion

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation:

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 5

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)3COH$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 6

Figure 3

Conclusion

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 7

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CuLi$ reacts with propionyl chloride at $−78°C$ followup by hydrolysis to from a ketone. The alkyl part of $(CH3)2CuLi$ substitutes the chloro group of acyl chloride.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 8

Figure 4

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation:

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown below.

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. propionyl chloride reduces similary as carbonylic acid with $H2$ , $Pd$ catalyst in the presence of quinolinesulfur poison to an aldehyde. The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 12

Figure 5

Conclusion

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown in Figure 5

Interpretation Introduction

(f)

Interpretation:

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 14

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound undergoes Fredal craft acylation reaction with toluene in the presence of catalyst $AlCl3$ to from an acylated aromatic compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 15

Figure 6

Conclusion

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown in Figure 6.

Interpretation Introduction

(g)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 16

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CHNH2$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. Another molecule of $(CH3)2CHNH2$ reacts with the resultant compound to from an amide and ammonium chloride.

The corresponding chemical reaction is shown below.

Figure 7

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown in Figure 7.

Interpretation Introduction

(h)

Interpretation:

The major product of the reaction between propionyl chloride and sodium benzoate is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and sodium benzoate is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 18

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound sodium benzoate reacts with propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 19

Figure 8

Conclusion

The major product of the reaction between propionyl chloride and sodium benzoate is shown in Figure 8.

Interpretation Introduction

(i)

Interpretation:

The major product of the reaction between propionylchloride, $p-cresol (4-methylphenol)$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 20

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound $p-cresol$ reacts with propionyl chloride in the presence of base pyridine. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 21

Figure 9

Conclusion

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown in Figure 9.

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In the scope of the SCH4U course, please thoroughly go through the second question

Answer 2

Question

Chapter 21, Problem 21.33AP

Interpretation Introduction

(a)

Interpretation:

The major product of the reaction between propionyl chloride and $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 1

Explanation of Solution

Propionyl chloride undergoes hydrolysis reaction to from propionic acid. The water molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form propionic acid.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 2

Figure 1

Conclusion

The major product of the reaction between propionyl chloride and $H2O$ is in Figure 1.

Interpretation Introduction

(b)

Interpretation:

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 3

Explanation of Solution

Propionyl chloride is a acyl chloride. It has a electrophilic carbonyl carbonyl carbon atom. The ethanethiol molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 4

Figure 2

Conclusion

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation:

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 5

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)3COH$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 6

Figure 3

Conclusion

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 7

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CuLi$ reacts with propionyl chloride at $−78°C$ followup by hydrolysis to from a ketone. The alkyl part of $(CH3)2CuLi$ substitutes the chloro group of acyl chloride.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 8

Figure 4

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation:

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown below.

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. propionyl chloride reduces similary as carbonylic acid with $H2$ , $Pd$ catalyst in the presence of quinolinesulfur poison to an aldehyde. The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 12

Figure 5

Conclusion

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown in Figure 5

Interpretation Introduction

(f)

Interpretation:

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 14

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound undergoes Fredal craft acylation reaction with toluene in the presence of catalyst $AlCl3$ to from an acylated aromatic compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 15

Figure 6

Conclusion

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown in Figure 6.

Interpretation Introduction

(g)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 16

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CHNH2$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. Another molecule of $(CH3)2CHNH2$ reacts with the resultant compound to from an amide and ammonium chloride.

The corresponding chemical reaction is shown below.

Figure 7

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown in Figure 7.

Interpretation Introduction

(h)

Interpretation:

The major product of the reaction between propionyl chloride and sodium benzoate is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and sodium benzoate is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 18

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound sodium benzoate reacts with propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 19

Figure 8

Conclusion

The major product of the reaction between propionyl chloride and sodium benzoate is shown in Figure 8.

Interpretation Introduction

(i)

Interpretation:

The major product of the reaction between propionylchloride, $p-cresol (4-methylphenol)$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 20

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound $p-cresol$ reacts with propionyl chloride in the presence of base pyridine. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 21

Figure 9

Conclusion

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown in Figure 9.

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Answer 3

Question

Chapter 21, Problem 21.33AP

Interpretation Introduction

(a)

Interpretation:

The major product of the reaction between propionyl chloride and $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 1

Explanation of Solution

Propionyl chloride undergoes hydrolysis reaction to from propionic acid. The water molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form propionic acid.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 2

Figure 1

Conclusion

The major product of the reaction between propionyl chloride and $H2O$ is in Figure 1.

Interpretation Introduction

(b)

Interpretation:

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 3

Explanation of Solution

Propionyl chloride is a acyl chloride. It has a electrophilic carbonyl carbonyl carbon atom. The ethanethiol molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 4

Figure 2

Conclusion

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation:

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 5

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)3COH$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 6

Figure 3

Conclusion

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 7

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CuLi$ reacts with propionyl chloride at $−78°C$ followup by hydrolysis to from a ketone. The alkyl part of $(CH3)2CuLi$ substitutes the chloro group of acyl chloride.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 8

Figure 4

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation:

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown below.

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. propionyl chloride reduces similary as carbonylic acid with $H2$ , $Pd$ catalyst in the presence of quinolinesulfur poison to an aldehyde. The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 12

Figure 5

Conclusion

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown in Figure 5

Interpretation Introduction

(f)

Interpretation:

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 14

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound undergoes Fredal craft acylation reaction with toluene in the presence of catalyst $AlCl3$ to from an acylated aromatic compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 15

Figure 6

Conclusion

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown in Figure 6.

Interpretation Introduction

(g)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 16

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CHNH2$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. Another molecule of $(CH3)2CHNH2$ reacts with the resultant compound to from an amide and ammonium chloride.

The corresponding chemical reaction is shown below.

Figure 7

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown in Figure 7.

Interpretation Introduction

(h)

Interpretation:

The major product of the reaction between propionyl chloride and sodium benzoate is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and sodium benzoate is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 18

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound sodium benzoate reacts with propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 19

Figure 8

Conclusion

The major product of the reaction between propionyl chloride and sodium benzoate is shown in Figure 8.

Interpretation Introduction

(i)

Interpretation:

The major product of the reaction between propionylchloride, $p-cresol (4-methylphenol)$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 20

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound $p-cresol$ reacts with propionyl chloride in the presence of base pyridine. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 21

Figure 9

Conclusion

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown in Figure 9.

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Answer 4

Question

Chapter 21, Problem 21.33AP

Interpretation Introduction

(a)

Interpretation:

The major product of the reaction between propionyl chloride and $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 1

Explanation of Solution

Propionyl chloride undergoes hydrolysis reaction to from propionic acid. The water molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form propionic acid.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 2

Figure 1

Conclusion

The major product of the reaction between propionyl chloride and $H2O$ is in Figure 1.

Interpretation Introduction

(b)

Interpretation:

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 3

Explanation of Solution

Propionyl chloride is a acyl chloride. It has a electrophilic carbonyl carbonyl carbon atom. The ethanethiol molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 4

Figure 2

Conclusion

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation:

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 5

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)3COH$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 6

Figure 3

Conclusion

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 7

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CuLi$ reacts with propionyl chloride at $−78°C$ followup by hydrolysis to from a ketone. The alkyl part of $(CH3)2CuLi$ substitutes the chloro group of acyl chloride.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 8

Figure 4

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation:

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown below.

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. propionyl chloride reduces similary as carbonylic acid with $H2$ , $Pd$ catalyst in the presence of quinolinesulfur poison to an aldehyde. The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 12

Figure 5

Conclusion

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown in Figure 5

Interpretation Introduction

(f)

Interpretation:

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 14

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound undergoes Fredal craft acylation reaction with toluene in the presence of catalyst $AlCl3$ to from an acylated aromatic compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 15

Figure 6

Conclusion

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown in Figure 6.

Interpretation Introduction

(g)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 16

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CHNH2$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. Another molecule of $(CH3)2CHNH2$ reacts with the resultant compound to from an amide and ammonium chloride.

The corresponding chemical reaction is shown below.

Figure 7

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown in Figure 7.

Interpretation Introduction

(h)

Interpretation:

The major product of the reaction between propionyl chloride and sodium benzoate is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and sodium benzoate is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 18

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound sodium benzoate reacts with propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 19

Figure 8

Conclusion

The major product of the reaction between propionyl chloride and sodium benzoate is shown in Figure 8.

Interpretation Introduction

(i)

Interpretation:

The major product of the reaction between propionylchloride, $p-cresol (4-methylphenol)$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 20

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound $p-cresol$ reacts with propionyl chloride in the presence of base pyridine. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 21

Figure 9

Conclusion

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown in Figure 9.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 21, Problem 21.33AP

Interpretation Introduction

(a)

Interpretation:

The major product of the reaction between propionyl chloride and $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 1

Explanation of Solution

Propionyl chloride undergoes hydrolysis reaction to from propionic acid. The water molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form propionic acid.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 2

Figure 1

Conclusion

The major product of the reaction between propionyl chloride and $H2O$ is in Figure 1.

Interpretation Introduction

(b)

Interpretation:

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 3

Explanation of Solution

Propionyl chloride is a acyl chloride. It has a electrophilic carbonyl carbonyl carbon atom. The ethanethiol molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 4

Figure 2

Conclusion

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation:

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 5

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)3COH$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 6

Figure 3

Conclusion

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown in Figure 3.

Interpretation Introduction

(d)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 7

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CuLi$ reacts with propionyl chloride at $−78°C$ followup by hydrolysis to from a ketone. The alkyl part of $(CH3)2CuLi$ substitutes the chloro group of acyl chloride.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 8

Figure 4

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown in Figure 4.

Interpretation Introduction

(e)

Interpretation:

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown below.

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. propionyl chloride reduces similary as carbonylic acid with $H2$ , $Pd$ catalyst in the presence of quinolinesulfur poison to an aldehyde. The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 12

Figure 5

Conclusion

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown in Figure 5

Interpretation Introduction

(f)

Interpretation:

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 14

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound undergoes Fredal craft acylation reaction with toluene in the presence of catalyst $AlCl3$ to from an acylated aromatic compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 15

Figure 6

Conclusion

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown in Figure 6.

Interpretation Introduction

(g)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 16

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CHNH2$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. Another molecule of $(CH3)2CHNH2$ reacts with the resultant compound to from an amide and ammonium chloride.

The corresponding chemical reaction is shown below.

Figure 7

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown in Figure 7.

Interpretation Introduction

(h)

Interpretation:

The major product of the reaction between propionyl chloride and sodium benzoate is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and sodium benzoate is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 18

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound sodium benzoate reacts with propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 19

Figure 8

Conclusion

The major product of the reaction between propionyl chloride and sodium benzoate is shown in Figure 8.

Interpretation Introduction

(i)

Interpretation:

The major product of the reaction between propionylchloride, $p-cresol (4-methylphenol)$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 20

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound $p-cresol$ reacts with propionyl chloride in the presence of base pyridine. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 21

Figure 9

Conclusion

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown in Figure 9.

Answer 6

Chapter 21, Problem 21.33AP

Interpretation Introduction

(a)

Interpretation:

The major product of the reaction between propionyl chloride and $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 1

Explanation of Solution

Propionyl chloride undergoes hydrolysis reaction to from propionic acid. The water molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form propionic acid.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 2

Figure 1

Conclusion

The major product of the reaction between propionyl chloride and $H2O$ is in Figure 1.

Answer 7

Chapter 21, Problem 21.33AP

Interpretation Introduction

(a)

Interpretation:

The major product of the reaction between propionyl chloride and $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a acid of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 8

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 1

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

Propionyl chloride undergoes hydrolysis reaction to from propionic acid. The water molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form propionic acid.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 2

Figure 1

Answer 13

Conclusion

The major product of the reaction between propionyl chloride and $H2O$ is in Figure 1.

Answer 14

Interpretation Introduction

(b)

Interpretation:

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 3

Explanation of Solution

Propionyl chloride is a acyl chloride. It has a electrophilic carbonyl carbonyl carbon atom. The ethanethiol molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 4

Figure 2

Conclusion

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown in Figure 2.

Answer 15

Interpretation Introduction

(b)

Interpretation:

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 16

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 3

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

Propionyl chloride is a acyl chloride. It has a electrophilic carbonyl carbonyl carbon atom. The ethanethiol molecule acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 4

Figure 2

Answer 21

Conclusion

The major product of the reaction between propionyl chloride, ethanethiol, and pyridine, at $0°C$ is shown in Figure 2.

Answer 22

Interpretation Introduction

(c)

Interpretation:

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 5

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)3COH$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 6

Figure 3

Conclusion

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown in Figure 3.

Answer 23

Interpretation Introduction

(c)

Interpretation:

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 24

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 5

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)3COH$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 6

Figure 3

Answer 29

Conclusion

The major product of the reaction between propionyl chloride, $(CH3)3COH$ , and pyridine is shown in Figure 3.

Answer 30

Interpretation Introduction

(d)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 7

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CuLi$ reacts with propionyl chloride at $−78°C$ followup by hydrolysis to from a ketone. The alkyl part of $(CH3)2CuLi$ substitutes the chloro group of acyl chloride.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 8

Figure 4

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown in Figure 4.

Answer 31

Interpretation Introduction

(d)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 32

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 7

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CuLi$ reacts with propionyl chloride at $−78°C$ followup by hydrolysis to from a ketone. The alkyl part of $(CH3)2CuLi$ substitutes the chloro group of acyl chloride.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 8

Figure 4

Answer 37

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CuLi$ at $−78°C$ , then with $H2O$ is shown in Figure 4.

Answer 38

Interpretation Introduction

(e)

Interpretation:

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown below.

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. propionyl chloride reduces similary as carbonylic acid with $H2$ , $Pd$ catalyst in the presence of quinolinesulfur poison to an aldehyde. The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 12

Figure 5

Conclusion

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown in Figure 5

Answer 39

Interpretation Introduction

(e)

Interpretation:

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 40

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown below.

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. propionyl chloride reduces similary as carbonylic acid with $H2$ , $Pd$ catalyst in the presence of quinolinesulfur poison to an aldehyde. The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 12

Figure 5

Answer 45

Conclusion

The major product of the reaction between propionyl chloride and $H2$ , $Pd$ catalyst (quinolinesulfur poison) is shown in Figure 5

Answer 46

Interpretation Introduction

(f)

Interpretation:

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 14

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound undergoes Fredal craft acylation reaction with toluene in the presence of catalyst $AlCl3$ to from an acylated aromatic compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 15

Figure 6

Conclusion

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown in Figure 6.

Answer 47

Interpretation Introduction

(f)

Interpretation:

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 48

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 14

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound undergoes Fredal craft acylation reaction with toluene in the presence of catalyst $AlCl3$ to from an acylated aromatic compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 15

Figure 6

Answer 53

Conclusion

The major product of the reaction between propionyl chloride and $AlCl3$ , toluene, then with $H2O$ is shown in Figure 6.

Answer 54

Interpretation Introduction

(g)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 16

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CHNH2$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. Another molecule of $(CH3)2CHNH2$ reacts with the resultant compound to from an amide and ammonium chloride.

The corresponding chemical reaction is shown below.

Figure 7

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown in Figure 7.

Answer 55

Interpretation Introduction

(g)

Interpretation:

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 56

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 16

Answer 57

Expert Solution

Answer 58

Expert Solution

Answer 59

Expert Solution

Answer 60

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. The compound $(CH3)2CHNH2$ acts as a nucleophile and attacks on the carbonyl carbon atom of propionyl chloride. Another molecule of $(CH3)2CHNH2$ reacts with the resultant compound to from an amide and ammonium chloride.

The corresponding chemical reaction is shown below.

Figure 7

Answer 61

Conclusion

The major product of the reaction between propionyl chloride and $(CH3)2CHNH2 (2 equiv.)$ is shown in Figure 7.

Answer 62

Interpretation Introduction

(h)

Interpretation:

The major product of the reaction between propionyl chloride and sodium benzoate is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and sodium benzoate is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 18

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound sodium benzoate reacts with propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 19

Figure 8

Conclusion

The major product of the reaction between propionyl chloride and sodium benzoate is shown in Figure 8.

Answer 63

Interpretation Introduction

(h)

Interpretation:

The major product of the reaction between propionyl chloride and sodium benzoate is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 64

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride and sodium benzoate is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 18

Answer 65

Expert Solution

Answer 66

Expert Solution

Answer 67

Expert Solution

Answer 68

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound sodium benzoate reacts with propionyl chloride. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 19

Figure 8

Answer 69

Conclusion

The major product of the reaction between propionyl chloride and sodium benzoate is shown in Figure 8.

Answer 70

Interpretation Introduction

(i)

Interpretation:

The major product of the reaction between propionylchloride, $p-cresol (4-methylphenol)$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 20

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound $p-cresol$ reacts with propionyl chloride in the presence of base pyridine. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 21

Figure 9

Conclusion

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown in Figure 9.

Answer 71

Interpretation Introduction

(i)

Interpretation:

The major product of the reaction between propionylchloride, $p-cresol (4-methylphenol)$ , and pyridine is to be predicated.

Concept introduction:

Acid chloride is a type of carboxylic acid derivatives. The general formula of acid chloride is $RCOCl$ . The compound contains a carbonyl group attached to electronegative chloride atom. The electrophillic character of carbonyl carbon atom of acid chloride is high.

Answer 72

Expert Solution

Answer to Problem 21.33AP

The major product of the reaction between propionyl chloride, $p-cresol (4-methylphenol)$ , and pyridine is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 20

Answer 73

Expert Solution

Answer 74

Expert Solution

Answer 75

Expert Solution

Answer 76

Explanation of Solution

Propionyl chloride is an acyl chloride. It has an electrophilic carbonyl carbon atom. Th The compound $p-cresol$ reacts with propionyl chloride in the presence of base pyridine. The resultant compound lose $HCl$ molecule to form final compound.

The corresponding chemical reaction is shown below.

Organic Chemistry, Ebook And Single-course Homework Access, Chapter 21, Problem 21.33AP , additional homework tip 21

Figure 9