(a) Interpretation: Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained. Concept introduction: The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

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Answer 1

Question

Chapter 21, Problem 21.9P

Interpretation Introduction

(a)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(b)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(c)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 21, Problem 21.9P

Interpretation Introduction

(a)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(b)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(c)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

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Answer 3

Question

Chapter 21, Problem 21.9P

Interpretation Introduction

(a)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(b)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(c)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

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Answer 4

Question

Chapter 21, Problem 21.9P

Interpretation Introduction

(a)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(b)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(c)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

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Answer 5

Chapter 21, Problem 21.9P

Interpretation Introduction

(a)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(b)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Interpretation Introduction

(c)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Answer 6

Chapter 21, Problem 21.9P

Interpretation Introduction

(a)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Answer 7

Chapter 21, Problem 21.9P

Interpretation Introduction

(a)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or to donate its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Among the given two isomers, the one having greater basicity at the carbonyl oxygen is to be stated. The reason for the answer is to be explained.

Concept introduction:

The basicity is the ability to accept the proton or donates its electron density. A compound is said to be more basic if the conjugate acid formed by the compound is stable or less acidic.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains the basicity of a compound if the conjugate acid formed by it is stable or less acidic.

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Chapter 21 Solutions