
Concept explainers
(a)
Interpretation:
The difference between p−ethylbenzoic acid and ethyl benzoate using IR spectroscopy is to be stated.
Concept introduction:
Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and
(b)
Interpretation:
The difference between 2,4−dimethylbenzonitrile and N−methylbenzamide using proton NMR spectroscopy is to be stated.
Concept introduction:
Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. Proton NMR spectroscopy identifies the number of hydrogen atoms present in a molecule and the nature of the functional group. The value of peaks depends upon the chemical environment around the hydrogen atom.
(c)
Interpretation:
The difference between methyl propionate and ethyl acetate using proton NMR spectroscopy is to be stated.
Concept introduction:
Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. Proton NMR spectroscopy identifies the number of hydrogen atoms present in a molecule and the nature of the functional group. The value of peaks depends upon the chemical environment around the hydrogen atom.
(d)
Interpretation:
The difference between N-methylpropanamide and N−ethylacetamide using proton NMR spectroscopy is to be stated.
Concept introduction:
Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. Proton NMR spectroscopy identifies the number of hydrogen atoms present in a molecule and the nature of the functional group. The value of peaks depends upon the chemical environment around the hydrogen atom.
(e)
Interpretation:
The difference between ethyl butyrate and ethyl isobutyrate using 13C NMR spectroscopy is to be stated.
Concept introduction:
Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. The 13C NMR spectroscopy identifies the number of carbon atoms present in a molecule. The value of peaks depends upon the chemical environment.

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Chapter 21 Solutions
Organic Chemistry, Ebook And Single-course Homework Access
- Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c d) Calculate x for the 1645 cm-1 bandarrow_forwardConvert 1.38 eV into wavelength (nm) and wavenumber (cm-1) (c = 2.998 x 108 m/s; h = 6.626 x 10-34 J*s).arrow_forwardCan you help me understand the CBC method on metal bridging by looking at this problem?arrow_forward
- A partir de Aluminio y Co(NO3)2ꞏ6H2O, indicar las reacciones a realizar para obtener Azul de Thenard (Al2CoO4).arrow_forwardTo obtain Thenard Blue (Al2CoO4), the following reaction is correct (performed in an oven):Al(OH)3 + Co(OH)2 → Al2CoO4 + 4 H2Oarrow_forwardProblem 38 can u explain and solve thanks april 24arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning

