Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 21, Problem 21.39AP
Interpretation Introduction

(a)

Interpretation:

The structures of the products that would on the saponification of glyceryl trioleate with excess aqueous NaOH are to be predicted.

Concept introduction:

The reaction of an ester with a strong base is called saponification reaction. In saponification reaction, the ester bond breaks and results into two products: the salt of carboxylic acid and an alcohol. Lipid and Fat have ester linkages which can undergo saponification reaction.

Interpretation Introduction

(b)

Interpretation:

The product that would from when glyceryl trioleate undergoes catalytic hydrogenation reaction is to be predicted. The way in which the physical properties of the corresponding product differ from that of glyceryl trioleate is to be stated.

Concept introduction:

The addition of H2 in presence of a catalyst is known as catalytic hydrogenation reaction. This is a syn addition. The alkene is reduced to an alkane. In this reaction, the weak π bond of alkene and sigma bond between H2 is broken and two CH bonds are formed.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
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