Physics for Scientists and Engineers: Foundations and Connections
1st Edition
ISBN: 9781133939146
Author: Katz, Debora M.
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 20, Problem 44PQ
To determine
The explanation for which the Van der Waals equation reduced to
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
A)An ideal gas is confined to a container at a temperature of 330 K.What is the average kinetic energy of an atom of the gas? (Express your answer to two significant figures.)
B)2.00 mol of the helium is confined to a 2.00-L container at a pressure of 11.0 atm. The atomic mass of helium is 4.00 u, and the conversion between u and kg is 1 u = 1.661 ××10−27 kg.Calculate vrmsvrms. (Express your answer to three significant figures.)
C)A gold (coefficient of linear expansion α=14×10−6K−1α=14×10−6K−1 ) pin is exactly 4.00 cm long when its temperature is 180∘∘C. Find the decrease in long of the pin when it cools to 28.0∘∘C? (Express your answer to two significant figures.)
Consider 1 mole of a van der Waals gas.
(i)
Derive the expressions for the pressure, pc, temperature, Tc, and volume, Vc, in the critical
point of a van der Waals gas in terms of parameters a, b and R.
Derive the vdw equation in reduced coordinates p =,= 7, V = V/
(ii)
(iii)
Find how many times the gas temperature exceeds its critical temperature if the gas
pressure is 4 times as high as critical pressure and the volume of gas is equal to twice the
critical volume.
The mean free path λ and the mean collision time T of molecules of a diatomic gas with molecular mass 6.00 x10^-25 kg and radius r=1.0x10^-10m are measured.From these microscopic data we can obtain macroscopic properties such as temperature T and pressure P? If yes, consider λ=4.32x10^-8m and T=3.00x10^-10s and calculate T and P.a)It's not possible.b)Yes,T=150K and P~2.04atm.c)Yes,T=150K and P~4.08atm.d)Yes,T=300K and P~4.08atm.e)Yes,T=300K and P~5.32atmf)Yes,T=400K and P~4.08atmg)Yes,T=400K and P~5.32atm.
Chapter 20 Solutions
Physics for Scientists and Engineers: Foundations and Connections
Ch. 20.2 - In Example 20.1, we found that the rms value of a...Ch. 20.3 - If the temperature of a gas is doubled, what...Ch. 20.3 - Prob. 20.3CECh. 20.5 - Prob. 20.4CECh. 20.7 - Prob. 20.5CECh. 20.8 - Prob. 20.6CECh. 20 - Prob. 1PQCh. 20 - Prob. 2PQCh. 20 - Prob. 3PQCh. 20 - Prob. 4PQ
Ch. 20 - Prob. 5PQCh. 20 - Prob. 6PQCh. 20 - Prob. 7PQCh. 20 - Prob. 8PQCh. 20 - Particles in an ideal gas of molecular oxygen (O2)...Ch. 20 - Prob. 10PQCh. 20 - Prob. 11PQCh. 20 - Prob. 12PQCh. 20 - Prob. 13PQCh. 20 - Prob. 14PQCh. 20 - The mass of a single hydrogen molecule is...Ch. 20 - Prob. 16PQCh. 20 - The noble gases neon (atomic mass 20.1797 u) and...Ch. 20 - Prob. 18PQCh. 20 - Prob. 19PQCh. 20 - Prob. 20PQCh. 20 - Prob. 22PQCh. 20 - Prob. 23PQCh. 20 - Prob. 24PQCh. 20 - Prob. 25PQCh. 20 - Prob. 26PQCh. 20 - Prob. 27PQCh. 20 - Prob. 28PQCh. 20 - Consider the Maxwell-Boltzmann distribution...Ch. 20 - Prob. 30PQCh. 20 - Prob. 31PQCh. 20 - Prob. 32PQCh. 20 - Prob. 33PQCh. 20 - Prob. 34PQCh. 20 - Prob. 35PQCh. 20 - Prob. 36PQCh. 20 - Prob. 37PQCh. 20 - Prob. 38PQCh. 20 - Prob. 39PQCh. 20 - Prob. 40PQCh. 20 - Prob. 41PQCh. 20 - Prob. 42PQCh. 20 - Prob. 43PQCh. 20 - Prob. 44PQCh. 20 - Figure P20.45 shows a phase diagram of carbon...Ch. 20 - Prob. 46PQCh. 20 - Prob. 47PQCh. 20 - Consider water at 0C and initially at some...Ch. 20 - Prob. 49PQCh. 20 - Prob. 50PQCh. 20 - Prob. 51PQCh. 20 - Prob. 52PQCh. 20 - Prob. 53PQCh. 20 - Prob. 54PQCh. 20 - Prob. 55PQCh. 20 - Prob. 56PQCh. 20 - Consider again the box and particles with the...Ch. 20 - Prob. 58PQCh. 20 - The average kinetic energy of an argon atom in a...Ch. 20 - For the exam scores given in Table P20.60, find...Ch. 20 - Prob. 61PQCh. 20 - Prob. 62PQCh. 20 - Prob. 63PQCh. 20 - Prob. 64PQCh. 20 - Prob. 65PQCh. 20 - Prob. 66PQCh. 20 - Determine the rms speed of an atom in a helium...Ch. 20 - Consider a gas filling two connected chambers that...Ch. 20 - Prob. 69PQCh. 20 - Prob. 70PQCh. 20 - A 0.500-m3 container holding 3.00 mol of ozone...Ch. 20 - Prob. 72PQCh. 20 - Prob. 73PQ
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.Similar questions
- One process for decaffeinating coffee uses carbon dioxide ( M=44.0 g/mol) at a molar density of about 14,0 mol/m3 and a temperature of about 60 . (a) Is CO2 a solid, liquid, gas, or supercritical fluid under those conditions? (b) The van der Waals constants for carbon dioxide are a=0.3658 Pa m6/mol2 and b=4.286105 m3/mol. Using the van der Waals equation, estimate pressure of CO2 at that temperature and density. `arrow_forwardAn ideal gas is contained in a vessel at 300 K. The temperature of the gas is then increased to 900 K. (i) By what factor does the average kinetic energy of the molecules change, (a) a factor of 9, (b) a factor of 3, (c) a factor of 3, (d) a factor of 1, or (e) a factor of 13? Using the same choices as in part (i), by what factor does each of the following change: (ii) the rms molecular speed of the molecules, (iii) the average momentum change that one molecule undergoes in a collision with one particular wall, (iv) the rate of collisions of molecules with walls, and (v) the pressure of the gas?arrow_forwardIn the text, it was shown that N/V=2.681025m3 for gas at STP. (a) Show that this quantity is equivalent to N/V=2.681019cm3, as stated. (b) About how many atoms are mere in one m3 (a cubic micrometer) at STP? (c) What does your answer to part (b) imply about the separation of Mama and molecules?arrow_forward
- On a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?arrow_forwardCylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.arrow_forwardConsider an ideal monatomic gas. Here, take N as constant. We can take any two arguments like (p, V) or (E, V) or (p, T) and use them as variables representing the macro state. Using E = 3 / 2Nk (B) T for a monatomic ideal gas: A) Take (E, V) as macroscopic variables and express dW and dQ in terms of these variables (ie, dW = (...) dE + (...) dV and dQ = (...) dE + (. ..) Find the dV expressions). B) Check that dW and dQ are not full differentials. Prove that dQ / T is the exact differential. C) Repeat the above procedure, taking (p, T) as macroscopic variables.arrow_forward
- One cubic meter (1 m³) of mono-atomic ideal gas, is initially at room temperature and atmo- spheric pressure. The mass of a single molecule is 1.34 × 10-26 kg. 1. Find the root mean square speed, vrms, Oof the molecules by equating the kinetic energy of a single molecule to its average thermal energy. 2. Knowing that the gas obeys the Maxwell speed distribution 3/2 4nv²e-2T m mu2 D(v) = (0.2) 2πkT such that D(v)dv = 1. (0.3) Find the expression of the probability (do not do the integral) that a particular molecule is moving with a speed faster than 2000m/s. 3. The gas is heated at constant pressure until it triples in volume. Calculate the increase in its entropy.arrow_forwardThe potential function between molecules of a simple non-polar gas, when the mass centres are separated by a distance r, is given by the well-known expressions: p(r) = 4€[(÷) '? – (#)*] For this gas in question: e/k = 120K and b, = No =0.063 m³/kmol a) What is the magnitude of the potential o(r) at its minimum?arrow_forwardA container encloses 2 mol of an ideal gas that has molar mass M1 and 0.5 mol of a second ideal gas that has molar mass M2 = 3M1. What fraction of the total pressure on the container wall is attributable to the second gas? (The kinetic theory explanation of pressure leads to the experimentally discovered law of partial pressures for a mixture of gases that do not react chemically: The total pressure exerted by the mixture is equal to the sum of the pressures that the several gases would exert separately if each were to occupy the vessel alone. The molecule–vessel collisions of one type would not be altered by the presence of another type.)arrow_forward
- 2. A box contains N =100 identical gas molecules equally divided between its two halves. What are (a) the multiplicity of the central configuration? (b) the total number of microstates? (c) the percentage of time the system spends in the central configuration? (d) the trend of the percentage of time the system spends in the central configuration as N increases? 10 atm 3. One mole if ideal monatomic is taken through the reversible P-V cycle shown. Find (a) the energy added to the gas as heat (b) the energy leaving the gas as heat (c) the net work done by the gas adiabatic (d) the efficiency of the cycle 1.00 x 10-3 m 8.00 x 10-3 marrow_forwardYou are studying a gas known as "gopherine" and looking in the literature you find that someone has reported the partition function for one molecule of this gas, 5/2 AzT q(V, T) = ) %3D h?m Assume that the molecules are independent and indistinguishable. Derive the expressions for the energy, (E), for this gas. Give your answers in terms of N, kg, T. V and the constants A and B. O (E) = NkaT ㅇ (E) =D NkaT ㅇ (E) %3D NkaT- O (E) = ANKET - O (E) = - T ㅇ (E)=D 쑤-arrow_forwardWhat is the average translational kinetic energy of an ideal gas at 868 K? (The value of Boltzmann's constant is 1.38 x 10-23 J/K.) O 5.99 x 10-21 , O 1.23 x 10-17, O 4.11 x 10-19, 1.80 x 10-20,arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physics for Scientists and Engineers: Foundations...PhysicsISBN:9781133939146Author:Katz, Debora M.Publisher:Cengage LearningPrinciples of Physics: A Calculus-Based TextPhysicsISBN:9781133104261Author:Raymond A. Serway, John W. JewettPublisher:Cengage LearningPhysics for Scientists and Engineers, Technology ...PhysicsISBN:9781305116399Author:Raymond A. Serway, John W. JewettPublisher:Cengage Learning
- Modern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage LearningCollege PhysicsPhysicsISBN:9781938168000Author:Paul Peter Urone, Roger HinrichsPublisher:OpenStax College
Physics for Scientists and Engineers: Foundations...
Physics
ISBN:9781133939146
Author:Katz, Debora M.
Publisher:Cengage Learning
Principles of Physics: A Calculus-Based Text
Physics
ISBN:9781133104261
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
Physics for Scientists and Engineers, Technology ...
Physics
ISBN:9781305116399
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning
College Physics
Physics
ISBN:9781938168000
Author:Paul Peter Urone, Roger Hinrichs
Publisher:OpenStax College