Problem 20.1E Problem 20.2E: The oxidation-reduction reaction between iron metal and aqueous permanganate ions in acidic solution... Problem 20.3E: The oxidation-reduction reaction between iron metal and aqueous permanganate ions in acidic solution... Problem 20.4E: The rate of the reaction HOCH2CH2NO2+2HNO2NO2CH2CH2NO2+2H2O is 0.045molHNO2/s. What are the rates of... Problem 20.5E: For a certain reaction between NO and O2, the rate law is rate=k[NO]2[O2] What is the order with... Problem 20.6E: For a reaction between SO2 and Cl2, the rate law is rate=k[Cl2] What is the order with respect to... Problem 20.7E: Consider the chemical reaction A+B+Cproducts Determine the order with respect to A,B,andC, and... Problem 20.8E: For the chemical reaction Mn2+(aq)+H2O2(aq)products The following data are collected: [Mn2+],M... Problem 20.9E: Explain how a species might be part of a rate law but not part of a balanced chemical reaction. Problem 20.10E: Refer to Example 20.2 and explain whether any useful information can be obtained by comparing the... Problem 20.11E: Rate law experiments dont always give data in the form of a rate in moles per second. Some of them... Problem 20.12E Problem 20.13E: What must the units on k be for the following rate law? rate=k[A]2[B]2 Problem 20.14E: What must the units on k be for the following rate law? rate=k[A]1 Problem 20.15E: The reaction 2O33O2 has first-order kinetics and a rate law constant of 7.66103s1. If the initial... Problem 20.17E: Digestive processes are first-order processes. The absorption of Fe2+ by the small intestine has a... Problem 20.18E Problem 20.19E: Derive equation 20.15. Problem 20.20E Problem 20.21E: To a very good approximation, the cooling of a hot body to room temperature (298K) follows... Problem 20.22E: Assume that thermal decomposition of mercuric oxide, HgO, follows first-order kinetics. It can be... Problem 20.23E Problem 20.24E Problem 20.25E: Derive equation 20.22. Problem 20.26E: a Write a rate law and an integrated rate law for a chemical reaction that follows third-order... Problem 20.27E: Derive an expression for the half-life of a a third order reaction;b a reaction whose order is =1; c... Problem 20.28E Problem 20.29E: Rewrite equation 20.27 so that it has the form of a straight-line equation, and identify the... Problem 20.30E: One can also define a third-life, t1/3, which is the amount of time necessary for one-third of an... Problem 20.31E: The decomposition of NH3: 2NH3N2+3H2 is a zeroth-order reaction that, at elevated temperatures, has... Problem 20.32E Problem 20.33E Problem 20.34E: When ionic compounds crystallize from a supersaturated solution, the crystallization front that is,... Problem 20.35E: An aqueous reaction that uses the solvent H2O as a reactant has a given rate law of rate=k[H2O][A]... Problem 20.36E: The rate law for the reaction C6H5OH+HNO2[OHcatalyst]C6H5NO2+H2O is rate=k[C6H5OH][HNO2] At 35.0C,... Problem 20.37E: If a reaction has the same rate constant, what time does it take for a reactant to decrease by 5... Problem 20.38E: List at least four experimentally determined parameters that you, an experimenter, can define when... Problem 20.39E Problem 20.40E Problem 20.41E Problem 20.42E Problem 20.43E: What is the value of the equilibrium constant of a reaction if the forward rate constant was... Problem 20.44E Problem 20.45E Problem 20.46E: Show how equation 20.33 reduces to a simpler form of an integrated first-order rate law when the... Problem 20.47E: Write expressions like equation 20.37 for a set of three parallel reactions from the same reactant.... Problem 20.48E Problem 20.49E Problem 20.50E Problem 20.51E Problem 20.52E Problem 20.53E Problem 20.54E Problem 20.55E: For what values of time, t, will 210Bi and 206Pb be at a maximum? See exercise 20.54. Problem 20.56E Problem 20.57E: An interesting pair of consecutive reactions involve the absorption of ethyl alcohol by the body,... Problem 20.58E: Find limiting forms of equation 20.47 for a k1>>k2 and b k1<<k2. Problem 20.59E Problem 20.60E Problem 20.61E Problem 20.62E Problem 20.63E: At room temperature (22C), the rate constant for proton transfer between water molecules in solution... Problem 20.64E: Recently, researchers studying the kinetics of metal atom reactions with small gas molecules... Problem 20.65E: A reaction has k=1.771061/(Ms) at 25.0C and an activation energy of 2.00kJ/mol. a What order is the... Problem 20.66E Problem 20.67E Problem 20.68E Problem 20.69E: Nitric oxide, NO, is known to break down ozone, O3, by the following bimolecular reaction:... Problem 20.70E: a Suggest a mechanism for the bromination of ethane: Br2+CH3CH3CH3CH2Br+HBr b Would you expect that... Problem 20.71E Problem 20.72E Problem 20.73E: Determine a rate law for the chlorination of methane assuming that the first step is the... Problem 20.74E: Determine a rate law for the chlorination of methane assuming that the second step is the... Problem 20.75E: A proposed mechanism for the gas-phase chlorination of methane is... Problem 20.76E Problem 20.77E: The nitration of methanol, CH3OH, by nitrous acid is thought to proceed via the following mechanism:... Problem 20.78E Problem 20.79E: Many gas-phase reactions require some inert body, usually represented as M, to absorb or supply... Problem 20.80E Problem 20.81E: Carbonic anhydrase, an enzyme whose substrate is CO2, has a K of 12mM. When the concentration of CO2... Problem 20.82E: Show that another form of the Michaelis-Menten equation is rate=V[S]K+[S] Problem 20.83E Problem 20.84E Problem 20.85E Problem 20.86E Problem 20.87E: Pyrolysis involves heating compounds to break them into smaller molecules, and typically involves... Problem 20.88E Problem 20.89E: Label the elementary processes for the reaction between H2 and O2 see section 20.7 as initiation,... Problem 20.90E Problem 20.91E: What are the rate laws of mechanisms 1 and 2 for oscillating reactions if the second reactions were... Problem 20.92E: Estimate G for an elementary process whose rate constant k is 8.5101M1s1 at 450K. Problem 20.93E Problem 20.94E Problem 20.95E Problem 20.96E: For the following two reactions H+Cl2HCl+Cl H+Br2HBr+Br the first reaction has a lower value of A... Problem 20.97E Problem 20.98E Problem 20.99E Problem 20.100E: Consider a reaction that has two parallel pathways both first-order to products. Pathway 1, leading... Problem 20.101E: Consider a set of first-order consecutive reactions ABC. The rate constants are 8.4104s1 and... Problem 20.102E format_list_bulleted