Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 20, Problem 20.90E
Interpretation Introduction
Interpretation:
The rate laws for elementary processes for the proposed mechanisms 1 and 2 of oscillating reactions are to be stated.
Concept introduction:
The reactions in which the concentration of the intermediate species changes with time in a periodic manner are known as oscillating reactions. The concentration oscillation includes color change cycle or formation of gaseous products periodically or any measurable change in the concentration of some species.
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b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
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membered ring
the expected product,
containing two fused rings
H3C-I
(H3C)2CuLi
an enolate
b.
H3C
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1.
2. H3O+
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MgBr
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Predict the major products of this reaction:
excess
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?
A
Note that the first reactant is used in excess, that is, there is much more of the first reactant than the second.
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Chapter 20 Solutions
Physical Chemistry
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Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY