The acetal or hemiacetal grouping of gentiobiose, reducing or nonreducing property of gentiobiose and the link between two monosaccharides has to be determined. Concept introduction: Reducing sugar: Sugars that contain aldehyde or a free ketone groups that are oxidized to carboxylic acids are classified as reducing sugars. So, the open chain form of sugars can reduce certain oxidizing agents (Tollens’, Fehling’s and Benedict’s) and become carboxylic acids. Anomeric position is carried by a – O H group for Hemiacetal sugars. Anomeric position is carried by an alkoxy group for acetal sugars. Hemiacetal sugars are in equilibrium with their open chain form. Acetal sugars are not in equilibrium with their open chain form. The linkage between monosaccharides in a disaccharide is referred to as a glycosidic linkage. Two β-D-glucose are connected to form Gentiobiose by the β-1,6 glycosidic linkage .

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 20.67AP

Interpretation Introduction

Interpretation:

The acetal or hemiacetal grouping of gentiobiose, reducing or nonreducing property of gentiobiose and the link between two monosaccharides has to be determined.

Concept introduction:

Reducing sugar: Sugars that contain aldehyde or a free ketone groups that are oxidized to carboxylic acids are classified as reducing sugars. So, the open chain form of sugars can reduce certain oxidizing agents (Tollens’, Fehling’s and Benedict’s) and become carboxylic acids.

Anomeric position is carried by a –OH group for Hemiacetal sugars.

Anomeric position is carried by an alkoxy group for acetal sugars.

Hemiacetal sugars are in equilibrium with their open chain form.

Acetal sugars are not in equilibrium with their open chain form.

The linkage between monosaccharides in a disaccharide is referred to as a glycosidic linkage. Two β-D-glucose are connected to form Gentiobiose by the β-1,6 glycosidic linkage.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Does trehalose (Problem 20.68) have an acetal grouping? A hemiacetal grouping? Do you expect trehalose to be a reducing or nonreducing sugar? Classify the linkage between the two monosaccharides.

Gentiobiose (D-Glc(β1→6)D-Glc) is a disaccharide found in some plantglycosides. Draw the structure of gentiobiose based on its abbreviated name. Is it a reducing sugar? Does it undergo mutarotation?

What is the pyranose/furanose ring structure of this sugar?

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 20.67AP

Interpretation Introduction

Interpretation:

The acetal or hemiacetal grouping of gentiobiose, reducing or nonreducing property of gentiobiose and the link between two monosaccharides has to be determined.

Concept introduction:

Reducing sugar: Sugars that contain aldehyde or a free ketone groups that are oxidized to carboxylic acids are classified as reducing sugars. So, the open chain form of sugars can reduce certain oxidizing agents (Tollens’, Fehling’s and Benedict’s) and become carboxylic acids.

Anomeric position is carried by a –OH group for Hemiacetal sugars.

Anomeric position is carried by an alkoxy group for acetal sugars.

Hemiacetal sugars are in equilibrium with their open chain form.

Acetal sugars are not in equilibrium with their open chain form.

The linkage between monosaccharides in a disaccharide is referred to as a glycosidic linkage. Two β-D-glucose are connected to form Gentiobiose by the β-1,6 glycosidic linkage.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 20.67AP

Interpretation Introduction

Interpretation:

The acetal or hemiacetal grouping of gentiobiose, reducing or nonreducing property of gentiobiose and the link between two monosaccharides has to be determined.

Concept introduction:

Reducing sugar: Sugars that contain aldehyde or a free ketone groups that are oxidized to carboxylic acids are classified as reducing sugars. So, the open chain form of sugars can reduce certain oxidizing agents (Tollens’, Fehling’s and Benedict’s) and become carboxylic acids.

Anomeric position is carried by a –OH group for Hemiacetal sugars.

Anomeric position is carried by an alkoxy group for acetal sugars.

Hemiacetal sugars are in equilibrium with their open chain form.

Acetal sugars are not in equilibrium with their open chain form.

The linkage between monosaccharides in a disaccharide is referred to as a glycosidic linkage. Two β-D-glucose are connected to form Gentiobiose by the β-1,6 glycosidic linkage.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 20.67AP

Interpretation Introduction