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Concept explainers
(a)
Interpretation:
The number of chiral carbon atoms present in the given carbohydrate has to be determined.
Concept introduction:
Carbohydrates are naturally-occurring polyhydroxy
Chiral carbon:
Chiral carbon is the one which is bonded to four different molecules or groups.
(b)
Interpretation:
The number of chiral carbon atoms present in the given carbohydrate has to be determined.
Concept introduction:
Carbohydrates are naturally-occurring polyhydroxy aldehydes and ketones.
Chiral carbon: Chiral carbon is the one which is bonded to four different molecules or groups.
(c)
Interpretation:
The number of chiral carbon atoms present in the given carbohydrate has to be determined.
Concept introduction:
Carbohydrates are naturally-occurring polyhydroxy aldehydes and ketones.
Chiral carbon: Chiral carbon is the one which is bonded to four different molecules or groups.
(d)
Interpretation:
The number of chiral carbon atoms present in the given carbohydrate has to be determined.
Concept introduction:
Carbohydrates are naturally-occurring polyhydroxy aldehydes and ketones.
Chiral carbon: Chiral carbon is the one which is bonded to four different molecules or groups.
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Chapter 20 Solutions
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
- Draw the product of this reaction. Ignore inorganic byproducts. H H ⚫OH HO- -H H- -OH H- -OH CH2OH Ag*, NH4OH, H2O Draw Fischer Projectionarrow_forwardDraw the product of this reaction. Ignore inorganic byproducts. H₂O -OH H ⚫OH HO H HO- CH2OH Cu2+ Draw Fischer Projectionarrow_forwardDraw the product of this reaction. Ignore inorganic byproducts. H、 H -OH H ⚫OH H -OH CH2OH Fehlings' solution ⑤ Draw Fischer Projectionarrow_forward
- Draw the product of this reaction. Ignore inorganic byproducts. HO C=0 H ⚫OH H ⚫OH HO- H HO H CH2OH Tollens' solution Draw Fischer Projectionarrow_forwardDraw the product of this reaction. Ignore inorganic byproducts. H-C=O HO H HO H H- ⚫OH HO H CH2OH HNO3, H2O Draw Fischer Projectionarrow_forwardDraw the product of this reaction. Ignore inorganic byproducts. HO HO- HO H HO ∙H HO CH2OH NaBH4, CH3OH Draw Fischer Projectionarrow_forward
- Draw the product of this reaction. Ignore inorganic byproducts. Но сво HO H HO H H OH H -OH CH2OH H2 Pd Draw Fischer Projectionarrow_forwardDraw the Haworth projection for Gulose-ẞ-1,6-sorbose and answer the following questions. (Gulose will be in the pyranose form and Sorbose will be in the furanose form) a. Label the reducing and nonreducing ends of the disaccharide b. Label the glycosidic bond c. Circle the anomeric carbons and label them as hemiacetals or acetals. d. Can this disaccharide undergo mutarotation?arrow_forwardDraw the product of the reaction below. Ignore inorganic byproducts. H OH HO HO HO ·H H OH H OH excess CH3CH2I KOHarrow_forward
- Draw the Haworth structures for the following: a. α-D-Gulopyranose b. ẞ-D-Sorbofuranose c. The two possible isomers of a-D-altrose (furanose and pyranose forms)arrow_forwardDraw the product of this reaction. Ignore inorganic byproducts. HO H ⚫OH HO- ∙H H- -OH H ⚫OH CH2OH HNO3, H2Oarrow_forwardDraw the product of the reaction below. Ignore inorganic byproducts. HO CH2OH OH OH OH excess CHзI Ag2Oarrow_forward
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