Study Guide for Campbell Biology
11th Edition
ISBN: 9780134443775
Author: Lisa A. Urry, Michael L. Cain, Steven A. Wasserman, Peter V. Minorsky, Jane B. Reece, Martha R. Taylor, Michael A. Pollock
Publisher: PEARSON
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Chapter 2, Problem 6IQ
a.
Summary Introduction
To determine: The valences of the four most common elements of living matter.
Introduction: In the simplest level of organization, the human body consists of various chemical structures. The substances that cannot be broken down into simpler substances by ordinary
b.
Summary Introduction
To draw: The Lewis dot structure of given structures.
Introduction: In Lewis dot structures, covalent bonds between the atoms in a molecule are shown with dots and element symbols. Each atom of the molecule is represented by the symbol of the particular element, whereas the valence electrons of the element are depicted as dots around the symbol.
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Draw all three staggered conformations for the following compound, viewed along the C₂-C3 bond. Determine which conformation is
the most stable, taking into account gauche interactions and hydrogen-bonding interactions. (J. Phys. Chem. A 2001, 105, 6991-6997)
Provide a reason for your choice by identifying all of the interactions that led to your decision.
H
H&COH
C₂
C3
HỌ CH
CH3
Which of the following is the most stable staggered conformer?
Me
H
OH
Me
OH
Me-
Me
Me
H
Conformer A
OH
OH
OH
HO
H
H
H
Conformer B
Conformer C
Me
Conformer B because the anti OH groups avoid hydrogen bonding, which is a destabilizing effect.
Conformer A because there are only two gauche interactions, and hydrogen bonding between the two OH groups is a
stabilizing effect.
Conformer C because there is no steric strain for Me-OH gauche interactions and hydrogen bonding between the two OH
groups is a stabilizing effect.
Conformer B because the large OH groups are anti to each other.
The “octet rule” in chemistry helps predict the types of bonds thatatoms will form. In general, an atom will be most stable if it fills itsouter shell of 8 electrons. Atoms with fewer than 4 valence electronstend to donate electrons and those with more than 4 valence electronstend to accept additional electrons; those with exactly 4 can do both.Using this rule, determine what category each of the followingelements falls into: N, S, C, P, O, H, Ca, Fe, and Mg. (You will needto work out the valence of the atoms.)
In an ammonia molecule, one nitrogen atom (atomic number = 7; 1s² 2s²2p³)
forms covalent bonds with three hydrogen atoms. Draw a diagram of an ammonia
molecule. Show all valence electrons, lone pairs, molecular geometry, and partial
charges (assume sp³ hybridization).
Chapter 2 Solutions
Study Guide for Campbell Biology
Ch. 2 - Fill in the names beside the symbols of the...Ch. 2 - The difference between the mass number and the...Ch. 2 - To move to a shell farther from the nucleus, an...Ch. 2 - Prob. 4IQCh. 2 - Fill in the blanks in the following concept map to...Ch. 2 - Prob. 6IQCh. 2 - Prob. 7IQCh. 2 - Prob. 8IQCh. 2 - Draw the structural formula of a water molecule,...Ch. 2 - Look at your sketch of a water molecule in...
Ch. 2 - Prob. 11IQCh. 2 - Prob. 1SYKCh. 2 - Atoms can have various numbers associated with...Ch. 2 - Prob. 3SYKCh. 2 - Prob. 1TYKCh. 2 - Prob. 2TYKCh. 2 - Prob. 3TYKCh. 2 - Prob. 4TYKCh. 2 - Radioactive isotopes can be used in studies of...Ch. 2 - Prob. 6TYKCh. 2 - Prob. 7TYKCh. 2 - Prob. 8TYKCh. 2 - Prob. 9TYKCh. 2 - Prob. 10TYKCh. 2 - Prob. 11TYKCh. 2 - Prob. 12TYKCh. 2 - Prob. 13TYKCh. 2 - Prob. 14TYKCh. 2 - Prob. 15TYKCh. 2 - A covalent bond between two atoms is likely to be...Ch. 2 - Prob. 17TYKCh. 2 - Prob. 18TYKCh. 2 - For questions 19-21, choose from the following...Ch. 2 - Prob. 20TYKCh. 2 - Prob. 21TYKCh. 2 - Prob. 22TYKCh. 2 - Prob. 23TYKCh. 2 - Prob. 24TYKCh. 2 - Prob. 25TYKCh. 2 - What is the difference between a molecule and a...Ch. 2 - Prob. 27TYKCh. 2 - Prob. 28TYK
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