The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated. Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix. Names of branches that occur commonly as side chains are listed below:

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Answer 1

Question

Chapter 2, Problem 46P

(a)

Interpretation Introduction

Interpretation: The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structure of 3-Methyl-3-propylpentane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

(c)

Interpretation Introduction

Interpretation: The structure of 1,1,1-Trifluoro-2-methylpropane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation: The structure of 4-(3-Bromobutyl)nonane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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22.7 Predict the monoalkylated products of the following reactions with benzene. (a) AlCl3 Ya (b) AlCl3 (c) H3PO4 (d) 22.8 Think-Pair-Share AICI3 The reaction below is a common electrophilic aromatic substitution. SO3 H₂SO4 SO₂H (a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile. (b) Sketch the reaction coordinate diagram, where the product is lower in energy than the starting reactant. (c) Which step in the reaction mechanism is highest in energy? Explain. (d) Which of the following reaction conditions could be used in an electrophilic aro- matic substitution with benzene to provide substituted phenyl derivatives? (i) AICI3 HNO3 H₂SO4 K2Cr2O7 (iii) H₂SO4 (iv) H₂PO₁

Is an acid-base reaction the only type of reaction that would cause leavening products to rise?

Answer 2

Question

Chapter 2, Problem 46P

(a)

Interpretation Introduction

Interpretation: The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structure of 3-Methyl-3-propylpentane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

(c)

Interpretation Introduction

Interpretation: The structure of 1,1,1-Trifluoro-2-methylpropane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation: The structure of 4-(3-Bromobutyl)nonane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 3

Question

Chapter 2, Problem 46P

(a)

Interpretation Introduction

Interpretation: The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structure of 3-Methyl-3-propylpentane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

(c)

Interpretation Introduction

Interpretation: The structure of 1,1,1-Trifluoro-2-methylpropane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation: The structure of 4-(3-Bromobutyl)nonane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 4

Question

Chapter 2, Problem 46P

(a)

Interpretation Introduction

Interpretation: The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structure of 3-Methyl-3-propylpentane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

(c)

Interpretation Introduction

Interpretation: The structure of 1,1,1-Trifluoro-2-methylpropane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation: The structure of 4-(3-Bromobutyl)nonane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 5

Chapter 2, Problem 46P

(a)

Interpretation Introduction

Interpretation: The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structure of 3-Methyl-3-propylpentane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

(c)

Interpretation Introduction

Interpretation: The structure of 1,1,1-Trifluoro-2-methylpropane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation: The structure of 4-(3-Bromobutyl)nonane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 6

Chapter 2, Problem 46P

(a)

Interpretation Introduction

Interpretation: The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 7

Chapter 2, Problem 46P

(a)

Interpretation Introduction

Interpretation: The structure of 4-Chloro-5-methylhexane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 8

(b)

Interpretation Introduction

Interpretation: The structure of 3-Methyl-3-propylpentane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structure of 3-Methyl-3-propylpentane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structure of 1,1,1-Trifluoro-2-methylpropane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 11

(c)

Interpretation Introduction

Interpretation: The structure of 1,1,1-Trifluoro-2-methylpropane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 12

(d)

Interpretation Introduction

Interpretation: The structure of 4-(3-Bromobutyl)nonane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 13

(d)

Interpretation Introduction

Interpretation: The structure of 4-(3-Bromobutyl)nonane corresponding to IUPAC name should be drawn and correct IUPAC name must be indicated.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 2.1 - Prob. 2.1E Ch. 2.1 - Prob. 2.2E Ch. 2.1 - Prob. 2.3E Ch. 2.1 - Prob. 2.5TIY Ch. 2.1 - Prob. 2.6E Ch. 2.1 - Prob. 2.7E Ch. 2.2 - Prob. 2.8E Ch. 2.3 - Prob. 2.9E Ch. 2.3 - Prob. 2.10E Ch. 2.3 - Prob. 2.11E

Solution Summary: The author explains that the structure of 4-Chloro-5-methylhexane should be drawn and correct IUPAC name must be indicated.

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Chapter 2 Solutions