EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 9781319188962
Author: VOLLHARDT
Publisher: VST
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Chapter 2.7, Problem 2.26E
Interpretation Introduction
Interpretation: Zigzag hashed-wedged line structures for
Concept introduction: The wedge bond depicts a bond that comes out of plane of paper, and the dash bond denotes bond that goes behind the plane of paper. This representation is used for correct three-dimensional representation of organic substrates as otherwise it might be difficult to visualize the orientation of different bonds in space. For example in methane 3D representation on plane two bonds in plane are shown by usual bonds, while one behind the plane and above the plane are denoted by dash and wedge type bonds as follows:
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1. Show the steps necessary to make 2-methyl-4-nonene using a
Wittig reaction. Start with triphenylphosphine and an alkyl
halide. After that you may use any other organic or inorganic
reagents.
2. Write in the product of this reaction:
CH3
CH₂
(C6H5)₂CuLi
H₂O+
3. Name this compound properly, including stereochemistry.
H₂C
H3C
CH3
OH
4. Show the step(s) necessary to transform the compound on the
left into the acid on the right.
Bri
CH2
5. Write in the product of this
LiAlH4
Br
H₂C
OH
What are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.
Chapter 2 Solutions
EBK ORGANIC CHEMISTRY
Ch. 2.1 - Prob. 2.1ECh. 2.1 - Prob. 2.2ECh. 2.1 - Prob. 2.3ECh. 2.1 - Prob. 2.5TIYCh. 2.1 - Prob. 2.6ECh. 2.1 - Prob. 2.7ECh. 2.2 - Prob. 2.8ECh. 2.3 - Prob. 2.9ECh. 2.3 - Prob. 2.10ECh. 2.3 - Prob. 2.11E
Ch. 2.3 - Prob. 2.12ECh. 2.3 - Prob. 2.13ECh. 2.3 - Prob. 2.14ECh. 2.3 - Prob. 2.15ECh. 2.3 - Prob. 2.17TIYCh. 2.3 - Prob. 2.19TIYCh. 2.5 - Prob. 2.20ECh. 2.6 - Prob. 2.21ECh. 2.6 - Prob. 2.22ECh. 2.6 - Prob. 2.23ECh. 2.6 - Prob. 2.25TIYCh. 2.7 - Prob. 2.26ECh. 2.9 - Prob. 2.28TIYCh. 2 - Prob. 31PCh. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - Prob. 35PCh. 2 - Prob. 36PCh. 2 - Prob. 37PCh. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - Prob. 40PCh. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Prob. 48PCh. 2 - Prob. 49PCh. 2 - Prob. 50PCh. 2 - Prob. 51PCh. 2 - Prob. 52PCh. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - Prob. 56PCh. 2 - Prob. 57PCh. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - Prob. 60PCh. 2 - Prob. 61PCh. 2 - Prob. 62PCh. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - Prob. 66P
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