Compounds A-D are to be ranked in order from the lowest to the highest boiling points. Concept introduction: Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

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Answer 1

Question

Chapter 2, Problem 2.54P

Interpretation Introduction

Interpretation:

Compounds A-D are to be ranked in order from the lowest to the highest boiling points.

Concept introduction:

Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater

polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

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CS2(g) → CS(g) + S(g) The rate law is Rate = k [CS2] where k = 1.6 × 10-6 s−1. S Calculate the half-life.

Answer 2

Question

Chapter 2, Problem 2.54P

Interpretation Introduction

Interpretation:

Compounds A-D are to be ranked in order from the lowest to the highest boiling points.

Concept introduction:

Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater

polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

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Answer 3

Question

Chapter 2, Problem 2.54P

Interpretation Introduction

Interpretation:

Compounds A-D are to be ranked in order from the lowest to the highest boiling points.

Concept introduction:

Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater

polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

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Answer 4

Question

Chapter 2, Problem 2.54P

Interpretation Introduction

Interpretation:

Compounds A-D are to be ranked in order from the lowest to the highest boiling points.

Concept introduction:

Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater

polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

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Answer 5

Chapter 2, Problem 2.54P

Interpretation Introduction

Interpretation:

Compounds A-D are to be ranked in order from the lowest to the highest boiling points.

Concept introduction:

Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater

polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

Answer 6

Chapter 2, Problem 2.54P

Interpretation Introduction

Interpretation:

Compounds A-D are to be ranked in order from the lowest to the highest boiling points.

Concept introduction:

Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater

polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

Answer 7

Chapter 2, Problem 2.54P

Interpretation Introduction

Interpretation:

Compounds A-D are to be ranked in order from the lowest to the highest boiling points.

Concept introduction:

Compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases from low to high as follows: Induced dipole - induced dipole < Dipole–dipole < Hydrogen bonding <Ion–dipole < Ion–ion The induced dipole-induced dipole interactions become stronger with a greater

polarizability. Dipole-dipole interactions become stronger with larger dipole moments. Hydrogen bonding becomes more extensive with a greater number of potential H-bond donors and H-bond acceptors.

Answer 8

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Answer 9

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Answer 11

Ch. 2 - Prob. 2.1P Ch. 2 - Prob. 2.2P Ch. 2 - Prob. 2.3P Ch. 2 - Prob. 2.4P Ch. 2 - Prob. 2.5P Ch. 2 - Prob. 2.6P Ch. 2 - Prob. 2.7P Ch. 2 - Prob. 2.8P Ch. 2 - Prob. 2.9P Ch. 2 - Prob. 2.10P

Solution Summary: The author explains that compounds with strong intermolecular forces have higher boiling points. Hydrogen bonding becomes more extensive with a greater number of potential hydrogen bond donors and acceptors.

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Chapter 2 Solutions