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Science Chemistry Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

The compound in the given pair that is expected to have a higher boiling point is to be predicted. The explanation for the prediction is to be given. Concept introduction: The compound with strong intermolecular forces has a higher boiling point. Hydrogen bonding requires a potential H-donor and acceptor atom. The electronegative atom such as N, O, or F attached directly to a hydrogen atom serves as a potential H-bond donor while atoms with lone pairs such as N, O, and F serve as potential H-bond acceptors. In the two molecules given, the greater the number of potential H-bond donors and acceptors, the greater is the strength of hydrogen bonding, thus, higher is the boiling point.

The compound in the given pair that is expected to have a higher boiling point is to be predicted. The explanation for the prediction is to be given. Concept introduction: The compound with strong intermolecular forces has a higher boiling point. Hydrogen bonding requires a potential H-donor and acceptor atom. The electronegative atom such as N, O, or F attached directly to a hydrogen atom serves as a potential H-bond donor while atoms with lone pairs such as N, O, and F serve as potential H-bond acceptors. In the two molecules given, the greater the number of potential H-bond donors and acceptors, the greater is the strength of hydrogen bonding, thus, higher is the boiling point.

Solution Summary: The author explains that the compound with strong intermolecular forces has a higher boiling point. The greater the number of potential H-bond donors and acceptors, the stronger the hydrogen bonding.

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

2nd Edition

ISBN: 9780393655551

Author: KARTY, Joel

Publisher: W. W. Norton & Company

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Question

Chapter 2, Problem 2.13P

Interpretation Introduction

Interpretation:

The compound in the given pair that is expected to have a higher boiling point is to be predicted. The explanation for the prediction is to be given.

Concept introduction:

The compound with strong intermolecular forces has a higher boiling point. Hydrogen bonding requires a potential H-donor and acceptor atom. The electronegative atom such as N, O, or F attached directly to a hydrogen atom serves as a potential H-bond donor while atoms with lone pairs such as N, O, and F serve as potential H-bond acceptors. In the two molecules given, the greater the number of potential H-bond donors and acceptors, the greater is the strength of hydrogen bonding, thus, higher is the boiling point.

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Chapter 2, Problem 2.12P

Chapter 2, Problem 2.14P

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Chapter 2 Solutions

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

Ch. 2 - Prob. 2.1P Ch. 2 - Prob. 2.2P Ch. 2 - Prob. 2.3P Ch. 2 - Prob. 2.4P Ch. 2 - Prob. 2.5P Ch. 2 - Prob. 2.6P Ch. 2 - Prob. 2.7P Ch. 2 - Prob. 2.8P Ch. 2 - Prob. 2.9P Ch. 2 - Prob. 2.10P

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