(a) Interpretation: Line structure using dash-wedge notation for the given molecule is to be drawn. Concept introduction: The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

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Answer 1

Question

Chapter 2, Problem 2.3P

Interpretation Introduction

(a)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(b)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(c)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

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Problem Draw a Lewis structure and identify the octet-rule exception for (a) H3PO4 (draw two resonance forms and select the more important); (b) BFCl2.Plan We draw each Lewis structure and examine it for exceptions to the octet rule.(a) The central atom is in Period 3, so it can have more than an octet.(b) The central atom is B, which can have fewer than an octet of electrons.

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Problem Draw Lewis structures for the following:(a) Ethylene (C2H4), the most important reactant in the manufacture of polymers(b) Nitrogen (N2), the most abundant atmospheric gasPlan We show the structure resulting from steps 1 to 4: placing the atoms, counting the total valence electrons, making single bonds, and distributing the remaining valence electrons in pairs to attain octets. Then we continue with step 5, if needed.

Answer 2

Question

Chapter 2, Problem 2.3P

Interpretation Introduction

(a)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(b)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(c)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

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Answer 3

Question

Chapter 2, Problem 2.3P

Interpretation Introduction

(a)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(b)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(c)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

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Answer 4

Question

Chapter 2, Problem 2.3P

Interpretation Introduction

(a)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(b)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(c)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

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Answer 5

Chapter 2, Problem 2.3P

Interpretation Introduction

(a)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(b)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Interpretation Introduction

(c)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Answer 6

Chapter 2, Problem 2.3P

Interpretation Introduction

(a)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Answer 7

Chapter 2, Problem 2.3P

Interpretation Introduction

(a)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Line structure using dash-wedge notation for the given molecule is to be drawn.

Concept introduction:

The dash-wedge notations are used to represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper. There are three types of lines used for such arrangements, straight line, dash line, and wedge line. The straight line represents the bond in the plane of paper. The dash line represents the bond pointing away from the observer that is below the plane of paper. The wedge line represents the bond pointing towards the observer that is above the plane of paper.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 2 - Prob. 2.1P Ch. 2 - Prob. 2.2P Ch. 2 - Prob. 2.3P Ch. 2 - Prob. 2.4P Ch. 2 - Prob. 2.5P Ch. 2 - Prob. 2.6P Ch. 2 - Prob. 2.7P Ch. 2 - Prob. 2.8P Ch. 2 - Prob. 2.9P Ch. 2 - Prob. 2.10P

Solution Summary: The author explains that dash-wedge notations represent the three dimensional arrangement of atoms or groups of molecules in the plane of paper.

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Chapter 2 Solutions