Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined. Concept Introduction: Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space. Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

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Answer 1

Question

Chapter 19, Problem 36E

(a)

Interpretation Introduction

Interpretation: Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(b)

Interpretation Introduction

Interpretation: The structure of trans-dichlorobis (ethylenediamine) cobalt(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(c)

Interpretation Introduction

Interpretation: The structure of cis-tetraamminechloronitrocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(d)

Interpretation Introduction

Interpretation: The structure of trans-tetraamminechloronitrotocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

(e)

Interpretation Introduction

Interpretation: The structure of trans-diaquabis (ethylenediamine) copper(II) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

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6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic. B₂2+ B22+, B2, C22, B22- and N22+ Molecular Orbital Diagram B2 C22- B22- N22+ Which molecule is paramagnetic?

Don't used hand raiting

EXERCISES: Complete the following exercises. You must show all work to receive full credit. 1. How many molecular orbitals can be built from the valence shell orbitals in O2? 2. Give the ground state electron configuration (e.g., 02s² 0*2s² П 2p²) for these molecules and deduce its bond order. Ground State Configuration Bond Order H2+ 02 N2

Answer 2

Question

Chapter 19, Problem 36E

(a)

Interpretation Introduction

Interpretation: Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(b)

Interpretation Introduction

Interpretation: The structure of trans-dichlorobis (ethylenediamine) cobalt(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(c)

Interpretation Introduction

Interpretation: The structure of cis-tetraamminechloronitrocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(d)

Interpretation Introduction

Interpretation: The structure of trans-tetraamminechloronitrotocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

(e)

Interpretation Introduction

Interpretation: The structure of trans-diaquabis (ethylenediamine) copper(II) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

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Answer 3

Question

Chapter 19, Problem 36E

(a)

Interpretation Introduction

Interpretation: Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(b)

Interpretation Introduction

Interpretation: The structure of trans-dichlorobis (ethylenediamine) cobalt(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(c)

Interpretation Introduction

Interpretation: The structure of cis-tetraamminechloronitrocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(d)

Interpretation Introduction

Interpretation: The structure of trans-tetraamminechloronitrotocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

(e)

Interpretation Introduction

Interpretation: The structure of trans-diaquabis (ethylenediamine) copper(II) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

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Answer 4

Question

Chapter 19, Problem 36E

(a)

Interpretation Introduction

Interpretation: Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(b)

Interpretation Introduction

Interpretation: The structure of trans-dichlorobis (ethylenediamine) cobalt(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(c)

Interpretation Introduction

Interpretation: The structure of cis-tetraamminechloronitrocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(d)

Interpretation Introduction

Interpretation: The structure of trans-tetraamminechloronitrotocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

(e)

Interpretation Introduction

Interpretation: The structure of trans-diaquabis (ethylenediamine) copper(II) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

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Answer 5

Chapter 19, Problem 36E

(a)

Interpretation Introduction

Interpretation: Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(b)

Interpretation Introduction

Interpretation: The structure of trans-dichlorobis (ethylenediamine) cobalt(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(c)

Interpretation Introduction

Interpretation: The structure of cis-tetraamminechloronitrocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

(d)

Interpretation Introduction

Interpretation: The structure of trans-tetraamminechloronitrotocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

(e)

Interpretation Introduction

Interpretation: The structure of trans-diaquabis (ethylenediamine) copper(II) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

Answer 6

Chapter 19, Problem 36E

(a)

Interpretation Introduction

Interpretation: Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

Answer 7

Chapter 19, Problem 36E

(a)

Interpretation Introduction

Interpretation: Thestructure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structure of trans-dichlorobis (ethylenediamine) cobalt(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structure of trans-dichlorobis (ethylenediamine) cobalt(II) needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structure of cis-tetraamminechloronitrocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

Answer 11

(c)

Interpretation Introduction

Interpretation: The structure of cis-tetraamminechloronitrocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in the same direction.

Answer 12

(d)

Interpretation Introduction

Interpretation: The structure of trans-tetraamminechloronitrotocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

Answer 13

(d)

Interpretation Introduction

Interpretation: The structure of trans-tetraamminechloronitrotocobalt(III) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

Answer 14

(e)

Interpretation Introduction

Interpretation: The structure of trans-diaquabis (ethylenediamine) copper(II) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

Answer 15

(e)

Interpretation Introduction

Interpretation: The structure of trans-diaquabis (ethylenediamine) copper(II) ion needs to be determined.

Concept Introduction:

Stereoisomer of coordination complexes or molecules have same structural formula but different arrangement of bonded atoms or group in 3-D space.

Geometrical isomers are the type of stereoisomers which can be defined as the complexes or molecules which have same structural formula but different orientation of bonded ligands in the plane. They are two types, in trans-isomer, similar ligands are placed in opposite direction whereas in cis-isomer same ligands are placed in same direction.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 19 - Prob. 1DQ Ch. 19 - Prob. 2DQ Ch. 19 - Prob. 3DQ Ch. 19 - Prob. 4DQ Ch. 19 - Prob. 5DQ Ch. 19 - Prob. 6E Ch. 19 - Prob. 7E Ch. 19 - What two first-row transition metals have...Ch. 19 - Prob. 9E Ch. 19 - Prob. 10E

Solution Summary: The author explains the structure of cis-dichloroethylenediamineplatinum(II) needs to be determined.

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Chapter 19 Solutions