Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
bartleby

Concept explainers

Question
Book Icon
Chapter 19, Problem 102CP

(a)

Interpretation Introduction

Interpretation: The appropriate crystal field diagram of the given complex ion needs to be determined, if ligand A lie on the z axis:

  Chemical Principles, Chapter 19, Problem 102CP , additional homework tip  1

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as t2g and eg orbitals. The electrons will fill according to their energy levels.

In octahedral complex, the t2g orbitals are lower energy orbitals in d-orbital splitting whereas eg orbitals are higher energy orbitals.

(b)

Interpretation Introduction

Interpretation: The approximate molecular orbital diagram for the given complex ion with assumption of only sigma bonding needs to be determined.

  Chemical Principles, Chapter 19, Problem 102CP , additional homework tip  2

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as t2g and eg orbitals. The electrons will fill according to their energy levels.

In octahedral complex, the t2g orbitals are lower energy orbitals in d-orbital splitting whereas eg orbitals are higher energy orbitals.

(c)

Interpretation Introduction

Interpretation: The difference in molecular orbital diagram and crystal field diagram for the given complex needs to be determined with respect to d-orbital. Also, the assumption needs to be reconstructed to achieve agreement between two.

  Chemical Principles, Chapter 19, Problem 102CP , additional homework tip  3Chemical Principles, Chapter 19, Problem 102CP , additional homework tip  4

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as t2g and eg orbitals. The electrons will fill according to their energy levels.

In octahedral complex, the t2g orbitals are lower energy orbitals in d-orbital splitting whereas eg orbitals are higher energy orbitals.

Blurred answer
Students have asked these similar questions
43) 10.00 ml of vinegar (active ingredient is acetic acid) is titrated to the endpoint using 19.32 ml of 0.250 M sodium hydroxide. What is the molarity of acetic acid in the vinegar? YOU MUST SHOW YOUR WORK. NOTE: MA x VA = MB x VB
424 Repon Sheet Rates of Chemical Reactions : Rate and Order of 1,0, Deception B. Effect of Temperature BATH TEMPERATURE 35'c Yol of Oh نام Time 485 Buret rend ing(n) 12 194 16. 6 18 20 10 22 24 14 115 95 14738 2158235 8:26 CMS 40148 Total volume of 0, collected Barometric pressure 770-572 ml mm Hg Vapor pressure of water at bath temperature (see Appendix L) 42.2 Slope Compared with the rate found for solution 1, there is Using the ideal gas law, calculate the moles of O; collected (show calculations) times faster 10 Based on the moles of O, evolved, calculate the molar concentration of the original 3% 1,0, solution (sho calculations)
Steps and explanation please

Chapter 19 Solutions

Chemical Principles

Ch. 19 - Prob. 11ECh. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - Prob. 14ECh. 19 - Prob. 15ECh. 19 - Define each of the following terms. a....Ch. 19 - Prob. 17ECh. 19 - When a metal ion has a coordination number of 2,...Ch. 19 - The compound cisplatin, Pt(NH3)2Cl2 , has been...Ch. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 22ECh. 19 - Prob. 23ECh. 19 - Prob. 24ECh. 19 - Prob. 25ECh. 19 - Prob. 26ECh. 19 - Prob. 27ECh. 19 - Prob. 28ECh. 19 - Prob. 29ECh. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Prob. 33ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - For the process Co(NH3)5Cl2++Cl2Co(NH3)4Cl2++NH3...Ch. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Prob. 41ECh. 19 - Prob. 42ECh. 19 - Prob. 43ECh. 19 - Prob. 44ECh. 19 - Prob. 45ECh. 19 - Prob. 46ECh. 19 - Prob. 47ECh. 19 - Prob. 48ECh. 19 - Prob. 49ECh. 19 - Prob. 50ECh. 19 - Prob. 51ECh. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Consider the complex ions...Ch. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - How many unpaired electrons are in the following...Ch. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Prob. 60ECh. 19 - Prob. 61ECh. 19 - Prob. 62ECh. 19 - Prob. 63ECh. 19 - Prob. 64ECh. 19 - Prob. 65ECh. 19 - Prob. 66ECh. 19 - Prob. 67ECh. 19 - Prob. 68ECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73AECh. 19 - Prob. 74AECh. 19 - Prob. 75AECh. 19 - Prob. 76AECh. 19 - Prob. 77AECh. 19 - Prob. 78AECh. 19 - Prob. 79AECh. 19 - Prob. 80AECh. 19 - Prob. 81AECh. 19 - Prob. 82AECh. 19 - Prob. 83AECh. 19 - Prob. 84AECh. 19 - Prob. 85AECh. 19 - Prob. 86AECh. 19 - Prob. 87AECh. 19 - Prob. 88AECh. 19 - Prob. 89AECh. 19 - Prob. 90AECh. 19 - Prob. 91AECh. 19 - Prob. 92AECh. 19 - Prob. 93AECh. 19 - Prob. 94AECh. 19 - Prob. 95AECh. 19 - Prob. 96AECh. 19 - Prob. 97CPCh. 19 - Prob. 98CPCh. 19 - Prob. 99CPCh. 19 - Prob. 100CPCh. 19 - Prob. 101CPCh. 19 - Prob. 102CPCh. 19 - Prob. 103CPCh. 19 - Prob. 104CP
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Principles of Modern Chemistry
    Chemistry
    ISBN:9781305079113
    Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
    Publisher:Cengage Learning
    Text book image
    Chemistry: Principles and Practice
    Chemistry
    ISBN:9780534420123
    Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
    Publisher:Cengage Learning
    Text book image
    Chemistry: The Molecular Science
    Chemistry
    ISBN:9781285199047
    Author:John W. Moore, Conrad L. Stanitski
    Publisher:Cengage Learning
  • Text book image
    Chemistry
    Chemistry
    ISBN:9781305957404
    Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
    Publisher:Cengage Learning
    Text book image
    Chemistry: An Atoms First Approach
    Chemistry
    ISBN:9781305079243
    Author:Steven S. Zumdahl, Susan A. Zumdahl
    Publisher:Cengage Learning
    Text book image
    Chemistry
    Chemistry
    ISBN:9781133611097
    Author:Steven S. Zumdahl
    Publisher:Cengage Learning
Text book image
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Cengage Learning