
Concept explainers
(a)
Interpretation: The appropriate crystal field diagram of the given complex ion needs to be determined, if ligand A lie on the z axis:
Concept Introduction:
Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as
In octahedral complex, the
(b)
Interpretation: The approximate molecular orbital diagram for the given complex ion with assumption of only sigma bonding needs to be determined.
Concept Introduction:
Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as
In octahedral complex, the
(c)
Interpretation: The difference in molecular orbital diagram and crystal field diagram for the given complex needs to be determined with respect to d-orbital. Also, the assumption needs to be reconstructed to achieve agreement between two.
Concept Introduction:
Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as
In octahedral complex, the

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Chapter 19 Solutions
Chemical Principles
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- Can you explain step by step behind what the synthetic strategy would be?arrow_forwardPlease explain step by step in detail the reasoning behind this problem/approach/and answer. thank you!arrow_forward2. Predict the product(s) that forms and explain why it forms. Assume that any necessary catalytic acid is present. .OH HO H₂N OHarrow_forward
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