
(a)
Interpretation: The value of
Given:
Concept Introduction:
Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as
In octahedral complex, the
(a)

Answer to Problem 101CP
Explanation of Solution
For
Calculate Ecell from Nernst equation:
(b)
Interpretation: The stronger oxidizing agent out of
Concept Introduction:
Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as
In octahedral complex, the
(b)

Answer to Problem 101CP
Explanation of Solution
For the given reaction;
A stronger oxidizing agent will be the more easily reduced species therefore the more positive standard reduction potential will be associated with strong oxidizing agent. Hence
(c)
Interpretation: The crystal field model for the stronger oxidizing agent out of
Concept Introduction:
Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion. On the basis of energy and degeneracy, the d-orbital can be classified as
In octahedral complex, the
(c)

Answer to Problem 101CP
Since en is a stronger-field ligand than H2O, the d-orbital splitting is larger for
Explanation of Solution
In aqueous solution,
Since, en is a stronger-field ligand than H2O, the d-orbital splitting is larger for
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Chapter 19 Solutions
Chemical Principles
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