Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Chapter 19, Problem 34E
(a)
Interpretation Introduction
Interpretation: The number of coordinate bond formed by acetylacetone (acacH)chelating ligand needs to be determined.
Concept Introduction: A coordination complex is composed of two main parts; metal atom/ ion and ligand. Ligands are the atom/ group of atom/ ion that can donate its extra pair of electrons to the electron deficient metal cation. It leads to the formation of coordinate bond between metal ion and ligand.
(b)
Interpretation Introduction
Interpretation: The number of coordinate bond formed by diethylenetriamine chelating ligand needs to be determined.
Concept Introduction: A coordination complex is composed of two main parts; metal atom/ ion and ligand. Ligands are the atom/ group of atom/ ion that can donate its extra pair of electrons to the electron deficient metal cation. It leads to the formation of coordinate bond between metal ion and ligand.
(c)
Interpretation Introduction
Interpretation: The number of coordinate bond formed by salen chelating ligand needs to be determined.
Concept Introduction: A coordination complex is composed of two main parts; metal atom/ ion and ligand. Ligands are the atom/ group of atom/ ion that can donate its extra pair of electrons to the electron deficient metal cation. It leads to the formation of coordinate bond between metal ion and ligand.
(d)
Interpretation Introduction
Interpretation: The number of coordinate bond formed by porphine chelating ligand needs to be determined.
Concept Introduction: A coordination complex is composed of two main parts; metal atom/ ion and ligand. Ligands are the atom/ group of atom/ ion that can donate its extra pair of electrons to the electron deficient metal cation. It leads to the formation of coordinate bond between metal ion and ligand.
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Draw the epoxide formed when the following alkene is treated with mCPBA. Click the "draw
structure" button to launch the drawing utility.
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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Chapter 19 Solutions
Chemical Principles
Ch. 19 - Prob. 1DQCh. 19 - Prob. 2DQCh. 19 - Prob. 3DQCh. 19 - Prob. 4DQCh. 19 - Prob. 5DQCh. 19 - Prob. 6ECh. 19 - Prob. 7ECh. 19 - What two first-row transition metals have...Ch. 19 - Prob. 9ECh. 19 - Prob. 10E
Ch. 19 - Prob. 11ECh. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - Prob. 14ECh. 19 - Prob. 15ECh. 19 - Define each of the following terms. a....Ch. 19 - Prob. 17ECh. 19 - When a metal ion has a coordination number of 2,...Ch. 19 - The compound cisplatin, Pt(NH3)2Cl2 , has been...Ch. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 22ECh. 19 - Prob. 23ECh. 19 - Prob. 24ECh. 19 - Prob. 25ECh. 19 - Prob. 26ECh. 19 - Prob. 27ECh. 19 - Prob. 28ECh. 19 - Prob. 29ECh. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Prob. 33ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - For the process Co(NH3)5Cl2++Cl2Co(NH3)4Cl2++NH3...Ch. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Prob. 41ECh. 19 - Prob. 42ECh. 19 - Prob. 43ECh. 19 - Prob. 44ECh. 19 - Prob. 45ECh. 19 - Prob. 46ECh. 19 - Prob. 47ECh. 19 - Prob. 48ECh. 19 - Prob. 49ECh. 19 - Prob. 50ECh. 19 - Prob. 51ECh. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Consider the complex ions...Ch. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - How many unpaired electrons are in the following...Ch. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Prob. 60ECh. 19 - Prob. 61ECh. 19 - Prob. 62ECh. 19 - Prob. 63ECh. 19 - Prob. 64ECh. 19 - Prob. 65ECh. 19 - Prob. 66ECh. 19 - Prob. 67ECh. 19 - Prob. 68ECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73AECh. 19 - Prob. 74AECh. 19 - Prob. 75AECh. 19 - Prob. 76AECh. 19 - Prob. 77AECh. 19 - Prob. 78AECh. 19 - Prob. 79AECh. 19 - Prob. 80AECh. 19 - Prob. 81AECh. 19 - Prob. 82AECh. 19 - Prob. 83AECh. 19 - Prob. 84AECh. 19 - Prob. 85AECh. 19 - Prob. 86AECh. 19 - Prob. 87AECh. 19 - Prob. 88AECh. 19 - Prob. 89AECh. 19 - Prob. 90AECh. 19 - Prob. 91AECh. 19 - Prob. 92AECh. 19 - Prob. 93AECh. 19 - Prob. 94AECh. 19 - Prob. 95AECh. 19 - Prob. 96AECh. 19 - Prob. 97CPCh. 19 - Prob. 98CPCh. 19 - Prob. 99CPCh. 19 - Prob. 100CPCh. 19 - Prob. 101CPCh. 19 - Prob. 102CPCh. 19 - Prob. 103CPCh. 19 - Prob. 104CP
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- What does the phrase 'fit for purpose' mean in relation to analytical chemistry? Please provide examples too.arrow_forwardFor each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects Resonance Effects Overall Electron-Density × NO2 ○ donating O donating O withdrawing O withdrawing O electron-rich electron-deficient no inductive effects O no resonance effects O similar to benzene E [ CI O donating withdrawing O no inductive effects Explanation Check ○ donating withdrawing no resonance effects electron-rich electron-deficient O similar to benzene © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accesarrow_forwardUnderstanding how substituents activate Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation HN NH2 Check X (Choose one) (Choose one) (Choose one) (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Aarrow_forward
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