ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 18.9, Problem 13P
Interpretation Introduction

Interpretation:

The conversion of given carboxylic acid to alcohol using a cyclic acetal protecting group with the necessary reagents is to be determined.

Concept introduction:

Aldehydes and ketones contain carbonyl functional group in their parent chain and are obtained by the oxidation of primary and secondary alcohols.

Acetal is an organic compound with general formula RHC(OR')2.

The two alkoxy groups (OR') are bonded with terminal carbon atom and the R' group can be same or different.

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.

Chapter 18 Solutions

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