ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 18, Problem 38P
Interpretation Introduction

Interpretation:

The synthesis of benzophenone from the given starting materials and any necessary inorganic reagents is to be described.

Concept introduction:

Friedal Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, synthesis of monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.

Grignard reagents are acidic. On reaction with water, they produce alkanes. The inorganic product Mg(OH)Br is referred to as basic bromide.

Pyridinium chlorochromate is an oxidising agent which can be used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Aldehydes react with diols to form hemiacetals. This reaction takes place in the presence of an acid.

Alkenes, on reaction with ozone which is followed by reduction with Zn in the presence of acetic acid, give carbonyl compounds.

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Chapter 18 Solutions

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