ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 18, Problem 52DSP
Interpretation Introduction

Interpretation:

The structures which are not the intermediates in the Baeyer-Villiger oxidation of cyclohexyl methyl ketone with peroxybenzoic acid are to be determined.

Concept Introduction:

During the Baeyer Villiger oxidation of ketones, an oxygen atom is inserted between the carbonyl group and one of the carbons attached to it. The product formed is an ester.

Usually, the oxygen atom is inserted between the carbonyl and the larger of the two groups attached to the carbonyl.

The ketone is converted to the conjugate acid of the ester.

The peroxy acid used is converted to the corresponding carboxylic acid.

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Chapter 18 Solutions

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