ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 18.7, Problem 9P
Interpretation Introduction

Interpretation: The expected cyanohydrin that would result by the hydrolysis of gynocardin has to be stated. Also, the corresponding ketone of this cyanohydrin has to be identified.

Concept introduction: Cyanohydrins refer to those compounds that consist of a hydroxy group and a nitrile group attached to the same carbon atom. They dissociate to produce hydrogen cyanide and one equivalent of an aldehyde or ketone on the basis of the structure of the starting material.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 18 Solutions

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