Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 18.7, Problem 60PP
Interpretation Introduction
Interpretation: To state the meaning of complementary base pairing.
Concept introduction: There are mainly two types of
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Students have asked these similar questions
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly
where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial
credit will be given. Note: You may need to draw in lone pairs before drawing the arrows.
A.
B.
H-Br
人
C
Θ
CI
H
Cl
Θ
+
Br
O
Chapter 18 Solutions
Basic Chemistry
Ch. 18.1 - Prob. 1PPCh. 18.1 - Prob. 2PPCh. 18.1 - Prob. 3PPCh. 18.1 - Prob. 4PPCh. 18.1 - Prob. 5PPCh. 18.1 - Prob. 6PPCh. 18.1 - Prob. 7PPCh. 18.1 - Prob. 8PPCh. 18.1 - Prob. 9PPCh. 18.1 - Prob. 10PP
Ch. 18.1 - Prob. 11PPCh. 18.1 - Prob. 12PPCh. 18.2 - Prob. 13PPCh. 18.2 - Prob. 14PPCh. 18.2 - Prob. 15PPCh. 18.2 - Prob. 16PPCh. 18.2 - Prob. 17PPCh. 18.2 - Prob. 18PPCh. 18.2 - Prob. 19PPCh. 18.2 - Prob. 20PPCh. 18.3 - Classify each of the following fatty acids as...Ch. 18.3 - Classify each of the following fatty acids as...Ch. 18.3 - Prob. 23PPCh. 18.3 - Prob. 24PPCh. 18.3 - Prob. 25PPCh. 18.3 - Olive oil is monounsaturated, whereas butter fat...Ch. 18.3 - Prob. 27PPCh. 18.3 - Use condensed structural formulas to write the...Ch. 18.3 - Prob. 29PPCh. 18.3 - Use condensed structural formulas to write the...Ch. 18.3 - Prob. 31PPCh. 18.3 - Prob. 32PPCh. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Prob. 35PPCh. 18.4 - Prob. 36PPCh. 18.4 - Give the name of the amino acid represented by...Ch. 18.4 - Prob. 38PPCh. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Prob. 40PPCh. 18.4 - Prob. 41PPCh. 18.4 - Prob. 42PPCh. 18.4 - Peptides isolated from rapeseed that may lower...Ch. 18.4 - Prob. 44PPCh. 18.5 - Prob. 45PPCh. 18.5 - Prob. 46PPCh. 18.5 - Prob. 47PPCh. 18.5 - Prob. 48PPCh. 18.5 - Prob. 49PPCh. 18.5 - What type of interaction would you expect between...Ch. 18.5 - Prob. 51PPCh. 18.5 - Prob. 52PPCh. 18.6 - Prob. 53PPCh. 18.6 - Match the terms, (1) active site, (2) lock-and-key...Ch. 18.6 - Prob. 55PPCh. 18.6 - Prob. 56PPCh. 18.7 - Prob. 57PPCh. 18.7 - Identify each of the following bases as a...Ch. 18.7 - Prob. 59PPCh. 18.7 - Prob. 60PPCh. 18.7 - Prob. 61PPCh. 18.7 - Prob. 62PPCh. 18.7 - Prob. 63PPCh. 18.7 - Prob. 64PPCh. 18.8 - Prob. 65PPCh. 18.8 - Prob. 66PPCh. 18.8 - Prob. 67PPCh. 18.8 - Prob. 68PPCh. 18.8 - Prob. 69PPCh. 18.8 - Prob. 70PPCh. 18.8 - Prob. 71PPCh. 18.8 - Prob. 72PPCh. 18.8 - Prob. 73PPCh. 18.8 - Prob. 74PPCh. 18 - Prob. 75UTCCh. 18 - Prob. 76UTCCh. 18 - Prob. 77UTCCh. 18 - Prob. 78UTCCh. 18 - Prob. 79UTCCh. 18 - Prob. 80UTCCh. 18 - Prob. 81UTCCh. 18 - Prob. 82UTCCh. 18 - Prob. 83UTCCh. 18 - Prob. 84UTCCh. 18 - Prob. 85UTCCh. 18 - Prob. 86UTCCh. 18 - Prob. 87APPCh. 18 - Prob. 88APPCh. 18 - Prob. 89APPCh. 18 - Prob. 90APPCh. 18 - Prob. 91APPCh. 18 - Prob. 92APPCh. 18 - Prob. 93APPCh. 18 - Prob. 94APPCh. 18 - Prob. 95APPCh. 18 - Prob. 96APPCh. 18 - Prob. 97APPCh. 18 - Prob. 98APPCh. 18 - Prob. 99APPCh. 18 - Prob. 100APPCh. 18 - Prob. 101CPCh. 18 - Prob. 102CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 104CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 106CPCh. 18 - Prob. 107CPCh. 18 - Prob. 108CPCh. 18 - Prob. 109CPCh. 18 - Prob. 110CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 112CPCh. 18 - A compound called butylated hydroxytoluene, or...Ch. 18 - Olive oil contains a high percentage of glyceryl...Ch. 18 - A sink drain can become clogged with solid fat...Ch. 18 - Prob. 44CICh. 18 - Prob. 45CICh. 18 - Prob. 46CI
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- 4. For the reactions below, draw the expected product. Be sure to indicate relevant stereochemistry or formal charges in the product structure. a) CI, H e b) H lux ligh Br 'Harrow_forwardArrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5) Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them. ▸ View Available Hint(s) Least acidity NH&F NaBr NaOH NH,Br NaCIO Reset Greatest acidityarrow_forward1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)arrow_forward
- Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…arrow_forwardPropose a synthesis pathway for the following transformations. b) c) d)arrow_forwardThe rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.arrow_forward
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