The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated. Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group. Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Question

3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.

Answer 1

Question

Chapter 18, Problem 18.67EP

(a)

Interpretation Introduction

Interpretation: The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The monosaccharide, ketohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization is to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The monosaccharide, aldopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The monosaccharide, ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.

1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat

3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

Answer 2

Question

Chapter 18, Problem 18.67EP

(a)

Interpretation Introduction

Interpretation: The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The monosaccharide, ketohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization is to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The monosaccharide, aldopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The monosaccharide, ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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Answer 3

Question

Chapter 18, Problem 18.67EP

(a)

Interpretation Introduction

Interpretation: The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The monosaccharide, ketohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization is to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The monosaccharide, aldopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The monosaccharide, ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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Answer 4

Question

Chapter 18, Problem 18.67EP

(a)

Interpretation Introduction

Interpretation: The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The monosaccharide, ketohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization is to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The monosaccharide, aldopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The monosaccharide, ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

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Answer 5

Chapter 18, Problem 18.67EP

(a)

Interpretation Introduction

Interpretation: The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(b)

Interpretation Introduction

Interpretation: The monosaccharide, ketohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization is to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(c)

Interpretation Introduction

Interpretation: The monosaccharide, aldopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

(d)

Interpretation Introduction

Interpretation: The monosaccharide, ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 6

Chapter 18, Problem 18.67EP

(a)

Interpretation Introduction

Interpretation: The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 7

Chapter 18, Problem 18.67EP

(a)

Interpretation Introduction

Interpretation: The monosaccharide, aldohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 8

(b)

Interpretation Introduction

Interpretation: The monosaccharide, ketohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization is to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 9

(b)

Interpretation Introduction

Interpretation: The monosaccharide, ketohexose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization is to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 10

(c)

Interpretation Introduction

Interpretation: The monosaccharide, aldopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 11

(c)

Interpretation Introduction

Interpretation: The monosaccharide, aldopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 12

(d)

Interpretation Introduction

Interpretation: The monosaccharide, ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 13

(d)

Interpretation Introduction

Interpretation: The monosaccharide, ketopentose whether forms a six-membered ring, a five- membered ring or a four- membered ring after intramolecular cyclization has to be stated.

Concept introduction: The simplest hydrolyzed form that is obtained from the carbohydrates is known as monosaccharide. Monosaccharide is categorized into two types. The first type of monosaccharide is aldoses and the second type of monosaccharide is ketoses. Aldoses sugar possesses aldehyde as a functional group and the ketoses sugar possesses ketone as a functional group.

Monosaccharides are also classified on the basis of the number of carbon atoms present in it. For example, the sugar that contains five carbon atoms is known as pentoses sugar and the sugar that contains six carbon atoms is known as hexoses sugar.

Answer 14

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Ch. 18.1 - In terms of mass percent, which of the following...Ch. 18.1 - Which of the following is the most abundant type...Ch. 18.2 - Which of the following statements concerning the...Ch. 18.2 - Prob. 2QQ Ch. 18.3 - Prob. 1QQ Ch. 18.3 - Prob. 2QQ Ch. 18.3 - Which of the following is not a possible value for...Ch. 18.3 - The complete hydrolysis of a polysaccharide...Ch. 18.4 - Prob. 1QQ Ch. 18.4 - Prob. 2QQ

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