The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn. Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Question

Identify each of the following Haworth projection formulas as an a-D monosaccharide or a ß D-monosaccharide.

Answer 1

Question

Chapter 18, Problem 18.129EP

(a)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(b)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(c)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis are to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(d)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

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Identify each of the following Haworth projection formulas as an a-D monosaccharide or a ß D-monosaccharide.

1) Please list all glycosidic linkages between each monosaccharide units. For example, α(1→4)2) Please discuss whether these oligo/polysaccharides would be reducing or non-reducing sugar. Remember to state your reasoning in complete sentence.

Consider the following statements: (1) The term sugar is a general designation for both monosaccharides and disaccharides. (2) The "penultimate carbon" in a monosaccharide is used to determine D- or L-configuration. (3) Sucrose is a reducing sugar and lactose is a nonreducing sugar. O Two of the three statements are true. All three statements are true. O Only one of the statements is true. None of the statements are true.

Answer 2

Question

Chapter 18, Problem 18.129EP

(a)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(b)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(c)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis are to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(d)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

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Answer 3

Question

Chapter 18, Problem 18.129EP

(a)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(b)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(c)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis are to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(d)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

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Answer 4

Question

Chapter 18, Problem 18.129EP

(a)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(b)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(c)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis are to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(d)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

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Answer 5

Chapter 18, Problem 18.129EP

(a)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(b)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(c)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis are to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

(d)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 6

Chapter 18, Problem 18.129EP

(a)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 7

Chapter 18, Problem 18.129EP

(a)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis are to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 11

(c)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis are to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 12

(d)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 13

(d)

Interpretation Introduction

Interpretation: The structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

Concept introduction: During a hydrolysis reaction, the glycosidic linkage between the two monosaccharide units is the point of attack. Two monosaccharides are released by the cleavage of the glycosidic linkage during hydrolysis. The H-atom in water is supplied to one monosaccharide and an –OH group entity is supplied to the other monosaccharide.

Answer 14

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Answer 25

Ch. 18.1 - In terms of mass percent, which of the following...Ch. 18.1 - Which of the following is the most abundant type...Ch. 18.2 - Which of the following statements concerning the...Ch. 18.2 - Prob. 2QQ Ch. 18.3 - Prob. 1QQ Ch. 18.3 - Prob. 2QQ Ch. 18.3 - Which of the following is not a possible value for...Ch. 18.3 - The complete hydrolysis of a polysaccharide...Ch. 18.4 - Prob. 1QQ Ch. 18.4 - Prob. 2QQ

Solution Summary: The author explains that the structures of the substances produced when the given disaccharide undergoes hydrolysis have to be drawn.

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Chapter 18 Solutions