Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 18, Problem 15P
Interpretation Introduction

Interpretation:

Ranking the given compounds in order of increasing acidity is to be represented.

Concept introduction:

Acidic hydrogen are the hydrogen atom that are attached to more electronegative atom like F, O, N, etc. and can dissociates into ions.

Acidic hydrogen means it has a tendency to easily release H+ ions in an aqueous solution.

An acid that completely dissociates in water is called a strong acid.

Activating groups are electron donating groups. They release pairs of electrons into a reaction center.

Deactivating group are electron withdrawing groups. They draw pairs of electrons away from a reaction center.

Electron withdrawing groups attract electron density toward itself and draw electrons away from the reaction centre.

Electron donating group donate electron density or releases electrons into the reaction centre.

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Rank the Acidity of the following sets of compounds. Give an explanation for the answers.
(a) Rank the following compounds in order of increasing acidity. (b) Which compound forms the strongest conjugate base?
I) The following reaction runs as written therefore... 1HClO2 +1NH3 ==>1ClO2- +1NH4+ (a)HClO2 is a weaker Bronsted base than NH4+(b)ClO2- is a stronger Bronsted base than NH3(c)HClO2 is a stronger Bronsted Acid than NH4+(d)None of those is correct.

Chapter 18 Solutions

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