(a)
Interpretation: The influence of adding more gas particles on the pressure of the contained gas is to be explained.
Concept Introduction: According to kinetic-molecular theory, gas particles travel arbitrarily and in straight lines until they collide elastically with either other gas particles or one of the container's walls. These contacts with the walls of the container determine the gas's pressure.
(a)
Answer to Problem 124A
Adding more gas particles will increase the pressure of the contained gas.
Explanation of Solution
Pressure increases favor the side with fewer particles, whereas pressure decreases favor the side with more particles. When the volume of the container remains the same, an increase in the number of gas molecules increases the pressure of the contained gas.
(b)
Interpretation: The influence of decreasing gas temperature on the pressure of the contained gas is to be explained.
Concept Introduction: According to kinetic-molecular theory, gas particles travel arbitrarily and in straight lines until they collide elastically with either other gas particles or one of the container's walls. These contacts with the walls of the container determine the gas's pressure.
(b)
Answer to Problem 124A
The decreasing gas temperature will decrease the pressure of the contained gas.
Explanation of Solution
When the temperature decreases, the average kinetic energy decreases, and the velocity of the gas particles when they strike the walls of the container decreases. The pressure is the force exerted by the particles per unit of area on the container. Therefore as the temperature decreases, the pressure of the contained gas must decrease.
(c)
Interpretation: The influence of reducing container volume on the pressure of the contained gas is to be explained.
Concept Introduction: According to kinetic-molecular theory, gas particles travel arbitrarily and in straight lines until they collide elastically with either other gas particles or one of the container's walls. These contacts with the walls of the container determine the gas's pressure.
(c)
Answer to Problem 124A
Reducing the container volume will increase the pressure of the contained gas.
Explanation of Solution
The volume of the container affects the pressure that is exerted on it. If the volume of a container is reduced, the available space for gas molecules to move around also becomes reduced. As a result, they will collide with the container's walls more often, increasing the pressure.
Chapter 18 Solutions
Chemistry 2012 Student Edition (hard Cover) Grade 11
- Denote the dipole for the indicated bonds in the following molecules. H3C ✓ CH3 B F-CCl 3 Br-Cl H3C Si(CH3)3 wwwwwww OH НО. HO HO OH vitamin C CH3arrow_forwardFor the SN2 reaction, draw the major organic product and select the correct (R) or (S) designation around the stereocenter carbon in the organic substrate and organic product. Include wedge-and-dash bonds and draw hydrogen on a stereocenter. Η 1 D EN Select Draw Templates More C H D N Erasearrow_forwardQ9: Explain why compound I is protonated on O while compound II is protonated on N. NH2 NH2 I IIarrow_forward
- AN IR spectrum, a 13 CMR spectrum, and a 1 HMR spectrum were obtained for an unknown structure with a molecular formula of C9H10. Draw the structure of this compound.arrow_forwardAN IR spectrum, a 13 CMR spectrum, and a 1 HMR spectrum were obtained for an unknown structure with a molecular formula of C9H10. Draw the structure of this compound.arrow_forward(a) What is the hybridization of the carbon in the methyl cation (CH3*) and in the methyl anion (CH3¯)? (b) What is the approximate H-C-H bond angle in the methyl cation and in the methyl anion?arrow_forward
- Q8: Draw the resonance structures for the following molecule. Show the curved arrows (how you derive each resonance structure). Circle the major resonance contributor.arrow_forwardQ4: Draw the Lewis structures for the cyanate ion (OCN) and the fulminate ion (CNO). Draw all possible resonance structures for each. Determine which form for each is the major resonance contributor.arrow_forwardIn the following molecule, indicate the hybridization and shape of the indicated atoms. CH3 N CH3 HÖ: H3C CI: ::arrow_forward
- Q3: Draw the Lewis structures for nitromethane (CH3NO2) and methyl nitrite (CH3ONO). Draw at least two resonance forms for each. Determine which form for each is the major resonance contributor.arrow_forwardQ1: Draw a valid Lewis structures for the following molecules. Include appropriate charges and lone pair electrons. If there is more than one Lewis structure available, draw the best structure. NH3 Sulfate Boron tetrahydride. C3H8 (linear isomer) OCN NO3 CH3CN SO2Cl2 CH3OH2*arrow_forwardQ2: Draw all applicable resonance forms for the acetate ion CH3COO. Clearly show all lone pairs, charges, and arrow formalism.arrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY