General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 17.5, Problem 17.14P
In addition to ethyl butanoate (Section 17.5), mangoes contain several other esters. Draw the structure ofeach of the following esters that has been isolated from the mango: (a) butyl formate; (b) ethyl octanoate;(c) ethyl propanoate.
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Arrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5)
Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them.
▸ View Available Hint(s)
Least acidity
NH&F NaBr NaOH
NH,Br NaCIO
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Greatest acidity
1. Consider the following molecular-level diagrams of a titration.
O-HA molecule
-Aion
°°
о
°
(a)
о
(b)
(c)
(d)
a. Which diagram best illustrates the microscopic representation for the
EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium.
hydroxide?
(e)
Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single
file upload below:
Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Chapter 17 Solutions
General, Organic, & Biological Chemistry
Ch. 17.1 - Draw out each compound to clearly show what groups...Ch. 17.1 - Prob. 17.2PCh. 17.1 - (a) Label each functional group in lisinopril, a...Ch. 17.2 - Give the IUPAC name for each compound. a. b. c.Ch. 17.2 - Give the structure corresponding to each IUPAC...Ch. 17.2 - Prob. 17.6PCh. 17.2 - Prob. 17.7PCh. 17.2 - Prob. 17.8PCh. 17.2 - Prob. 17.9PCh. 17.2 - Prob. 17.10P
Ch. 17.2 - Prob. 17.11PCh. 17.3 - Which compound in each pair has the higher boiling...Ch. 17.4 - Prob. 17.13PCh. 17.5 - In addition to ethyl butanoate (Section 17.5),...Ch. 17.6 - Prob. 17.15PCh. 17.6 - Prob. 17.16PCh. 17.6 - Prob. 17.17PCh. 17.6 - Prob. 17.18PCh. 17.6 - Prob. 17.19PCh. 17.7 - Prob. 17.20PCh. 17.7 - Ibuprofen is another pain reliever that is a...Ch. 17.8 - Prob. 17.22PCh. 17.8 - Prob. 17.23PCh. 17.8 - Prob. 17.24PCh. 17.8 - Prob. 17.25PCh. 17.8 - Prob. 17.26PCh. 17.9 - Prob. 17.27PCh. 17.9 - Prob. 17.28PCh. 17.9 - Prob. 17.29PCh. 17.9 - Prob. 17.30PCh. 17.9 - Prob. 17.31PCh. 17.9 - Prob. 17.32PCh. 17.10 - Prob. 17.33PCh. 17.10 - Prob. 17.34PCh. 17.10 - Prob. 17.35PCh. 17.11 - Prob. 17.36PCh. 17 - Prob. 17.37PCh. 17 - Prob. 17.38PCh. 17 - Prob. 17.39PCh. 17 - Prob. 17.40PCh. 17 - Prob. 17.41PCh. 17 - Prob. 17.42PCh. 17 - Prob. 17.43PCh. 17 - Prob. 17.44PCh. 17 - Prob. 17.45PCh. 17 - Prob. 17.46PCh. 17 - Prob. 17.47PCh. 17 - Give an acceptable name for each ester. a. CH3CO2(...Ch. 17 - Prob. 17.49PCh. 17 - Prob. 17.50PCh. 17 - Prob. 17.51PCh. 17 - Give an acceptable name for each compound.
a.
b....Ch. 17 - Prob. 17.53PCh. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Prob. 17.57PCh. 17 - Prob. 17.58PCh. 17 - Prob. 17.59PCh. 17 - Prob. 17.60PCh. 17 - Prob. 17.61PCh. 17 - Prob. 17.62PCh. 17 - Prob. 17.63PCh. 17 - Prob. 17.64PCh. 17 - Prob. 17.65PCh. 17 - Prob. 17.66PCh. 17 - What ester is formed when butanoic acid...Ch. 17 - Prob. 17.68PCh. 17 - Prob. 17.69PCh. 17 - Prob. 17.70PCh. 17 - Prob. 17.71PCh. 17 - Prob. 17.72PCh. 17 - Prob. 17.73PCh. 17 - Prob. 17.74PCh. 17 - Prob. 17.75PCh. 17 - Prob. 17.76PCh. 17 - Prob. 17.77PCh. 17 - Prob. 17.78PCh. 17 - Prob. 17.79PCh. 17 - Prob. 17.80PCh. 17 - Prob. 17.81PCh. 17 - Prob. 17.82PCh. 17 - Prob. 17.83PCh. 17 - Prob. 17.84PCh. 17 - Prob. 17.85PCh. 17 - Prob. 17.86PCh. 17 - What is the difference between saponification and...Ch. 17 - You have now learned three different types of...Ch. 17 - Draw the products formed in each reaction.
Ch. 17 - Prob. 17.90PCh. 17 - Answer the following questions about A, depicted...Ch. 17 - Answer the following questions about B, depicted...Ch. 17 - Prob. 17.93PCh. 17 - Prob. 17.94PCh. 17 - Prob. 17.95PCh. 17 - Prob. 17.96PCh. 17 - Prob. 17.97PCh. 17 - Prob. 17.98PCh. 17 - Prob. 17.99PCh. 17 - Prob. 17.100PCh. 17 - Prob. 17.101PCh. 17 - Prob. 17.102PCh. 17 - Prob. 17.103CPCh. 17 - Lactams can be hydrolyzed with base, just like...
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