The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected. Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group . Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

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Answer 1

Question

Chapter 17, Problem 84APP

(a)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(b)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to a hydroxyl group should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(c)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a nitrogen atom bonded to one or more carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(d)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to two carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

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1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Chapter 17, Problem 84APP

(a)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(b)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to a hydroxyl group should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(c)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a nitrogen atom bonded to one or more carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(d)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to two carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

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Answer 3

Question

Chapter 17, Problem 84APP

(a)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(b)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to a hydroxyl group should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(c)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a nitrogen atom bonded to one or more carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(d)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to two carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

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Answer 4

Question

Chapter 17, Problem 84APP

(a)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(b)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to a hydroxyl group should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(c)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a nitrogen atom bonded to one or more carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(d)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to two carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

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Answer 5

Chapter 17, Problem 84APP

(a)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(b)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to a hydroxyl group should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(c)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a nitrogen atom bonded to one or more carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

(d)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to two carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 6

Chapter 17, Problem 84APP

(a)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 7

Chapter 17, Problem 84APP

(a)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carboxyl group in which the hydrogen atom is replaced by a carbon atom should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 8

(b)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to a hydroxyl group should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 9

(b)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to a hydroxyl group should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 10

(c)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a nitrogen atom bonded to one or more carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 11

(c)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a nitrogen atom bonded to one or more carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 12

(d)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to two carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 13

(d)

Interpretation Introduction

Interpretation: The class of organic compound amongst the given that matches a compound containing a carbonyl group bonded to two carbon atoms should be selected.

Concept Introduction: A group of atoms or an atom which is responsible for the characteristic reactions of a particular compound is said to be the functional group. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 17.1 - Prob. 1PP Ch. 17.1 - Prob. 2PP Ch. 17.1 - Prob. 3PP Ch. 17.1 - Prob. 4PP Ch. 17.1 - Prob. 5PP Ch. 17.1 - Prob. 6PP Ch. 17.1 - Prob. 7PP Ch. 17.1 - Prob. 8PP Ch. 17.1 - Prob. 9PP Ch. 17.1 - Prob. 10PP

Solution Summary: The author explains that the class of organic compound that matches a carboxyl group should be selected. Every functional group shows distinctive chemical properties irrespective to the moiety to which it is attached.

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