Basic Chemistry
Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
Question
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Chapter 17, Problem 103APP

(a)

Interpretation Introduction

Interpretation: The name of the following compound should be determined:

Basic Chemistry, Chapter 17, Problem 103APP , additional homework tip  1

Concept Introduction: The group that contains a nitrogen atom attached to one or more carbon atoms is said to be an amine group, general representation of an amine group is R1R2R3-N.

The common name of amines are derived by naming the alkyl groups bonded to nitrogen atom in alphabetical order and then ending with word -amine.

(b)

Interpretation Introduction

Interpretation: The name of the following compound should be determined:

Basic Chemistry, Chapter 17, Problem 103APP , additional homework tip  2

Concept Introduction: An organic compound in which carboxy functional group that is -COOH is bonded to the carbon atom is said to be a carboxylic acid. The general formula for carboxylic acid is RCOOH or RCO2H. When -OH (hydroxyl group) of the carboxylic acid is replaced by nitrogen (-N) then it results in the formation of an amide.

The reaction which results in the formation of amide along with water on heating acids with amine or ammonia is said to be amidation.

So, in order to give the IUPAC name to the amides, the rules for naming carboxylic acid is followed and -oic acid of the carboxylic acid is replaced by amide.

In order to give the name to the amide group, the following steps are followed:

  1. The parent (longest) alkane chain is named as for carboxylic acids.
  2. The -oic acid in the name is changed to -amide.
  3. The numbering of the chain is done in such a way that amide group and substituents gets the smaller number.
  4. N-alkyl is used to show each alkyl group bonded to -N atom in the name for secondary and tertiary amides.

For number of carbons atoms chain, the prefix is given as:

Carbon-1  meth

Carbon-2  eth

Carbon-3  prop

Carbon-4  but

Carbon-5  pent

Carbon-6  hex

Carbon-7  hept

Carbon-8  oct

Carbon-9  non

Carbon-10  dec

In order to write the common name of the amides, the common of acids are written from which the amide has been formed by replacing -oic acid in name from -amide.

(c)

Interpretation Introduction

Interpretation: The name of the following compound should be determined:

Basic Chemistry, Chapter 17, Problem 103APP , additional homework tip  3

Concept Introduction: The group that contains a nitrogen atom attached to one or more carbon atoms is said to be an amine group, general representation of an amine group is R1R2R3-N.

The common name of amines are derived by naming the alkyl groups bonded to nitrogen atom in alphabetical order and then ending with word -amine.

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Chapter 17 Solutions

Basic Chemistry

Ch. 17.1 - Prob. 11PPCh. 17.1 - Draw the condensed structural formula for each of...Ch. 17.1 - Prob. 13PPCh. 17.1 - Prob. 14PPCh. 17.1 - Prob. 15PPCh. 17.1 - Prob. 16PPCh. 17.1 - Prob. 17PPCh. 17.1 - Prob. 18PPCh. 17.2 - Prob. 19PPCh. 17.2 - Identify each of the following as an alkane,...Ch. 17.2 - Prob. 21PPCh. 17.2 - Prob. 22PPCh. 17.2 - Prob. 23PPCh. 17.2 - Prob. 24PPCh. 17.2 - Draw the condensed structural formula for the...Ch. 17.2 - Prob. 26PPCh. 17.2 - Prob. 27PPCh. 17.2 - Prob. 28PPCh. 17.2 - Prob. 29PPCh. 17.2 - Prob. 30PPCh. 17.2 - Prob. 31PPCh. 17.2 - Prob. 32PPCh. 17.3 - Prob. 33PPCh. 17.3 - Prob. 34PPCh. 17.3 - Prob. 35PPCh. 17.3 - Draw the line-angle formula for each of the...Ch. 17.4 - Prob. 37PPCh. 17.4 - Prob. 38PPCh. 17.4 - Prob. 39PPCh. 17.4 - Write the common name for each of the following:...Ch. 17.4 - Draw the condensed structural and line-angle...Ch. 17.4 - Draw the condensed structural and line-angle...Ch. 17.5 - Write the common name for each of the following:Ch. 17.5 - Write the common name for each of the following:Ch. 17.5 - Prob. 45PPCh. 17.5 - Prob. 46PPCh. 17.5 - Prob. 47PPCh. 17.5 - Draw the condensed structural formula for a and b...Ch. 17.6 - Prob. 49PPCh. 17.6 - Write the IUPAC and common name (if any) for each...Ch. 17.6 - Prob. 51PPCh. 17.6 - Prob. 52PPCh. 17.6 - Prob. 53PPCh. 17.6 - Prob. 54PPCh. 17.6 - Prob. 55PPCh. 17.6 - Prob. 56PPCh. 17.6 - Prob. 57PPCh. 17.6 - Write the IUPAC and common names, if any, for each...Ch. 17.6 - Draw the condensed structural formulas for a and b...Ch. 17.6 - Draw the condensed structural formulas for a and b...Ch. 17.7 - Write the common name for each of the following:...Ch. 17.7 - Prob. 62PPCh. 17.7 - Prob. 63PPCh. 17.7 - Prob. 64PPCh. 17.7 - Prob. 65PPCh. 17.7 - Prob. 66PPCh. 17.7 - Prob. 67PPCh. 17.7 - Prob. 68PPCh. 17.7 - Prob. 69PPCh. 17.7 - Prob. 70PPCh. 17.7 - Prob. 71PPCh. 17.7 - Prob. 72PPCh. 17 - The chapter sections to review are shown in...Ch. 17 - The chapter sections to review are shown in...Ch. 17 - Prob. 75UTCCh. 17 - Prob. 76UTCCh. 17 - Prob. 77APPCh. 17 - Prob. 78APPCh. 17 - Prob. 79APPCh. 17 - Prob. 80APPCh. 17 - Prob. 81APPCh. 17 - Prob. 82APPCh. 17 - Prob. 83APPCh. 17 - Prob. 84APPCh. 17 - Classify each of the following according to its...Ch. 17 - Classify each of the following according to its...Ch. 17 - Name each of the following aromatic compounds:...Ch. 17 - Prob. 88APPCh. 17 - Prob. 89APPCh. 17 - Draw the structural formula for each of the...Ch. 17 - Prob. 91APPCh. 17 - Prob. 92APPCh. 17 - Draw the condensed structural formula for each of...Ch. 17 - Draw the condensed structural formula for each of...Ch. 17 - Write the IUPAC name for each of the following:...Ch. 17 - Write the IUPAC name for each of the following:...Ch. 17 - Draw the condensed structural formulas for a and b...Ch. 17 - Prob. 98APPCh. 17 - Prob. 99APPCh. 17 - Prob. 100APPCh. 17 - Prob. 101APPCh. 17 - Draw the condensed structural formula for each of...Ch. 17 - Prob. 103APPCh. 17 - Prob. 104APPCh. 17 - Prob. 105CPCh. 17 - Prob. 106CPCh. 17 - The following problems are related to the topics...Ch. 17 - Prob. 108CPCh. 17 - The following problems are related to the topics...Ch. 17 - Prob. 110CP
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