![Basic Chemistry](https://www.bartleby.com/isbn_cover_images/9780134878119/9780134878119_smallCoverImage.jpg)
Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 17, Problem 107CP
The following problems are related to the topics in this chapter. However, they do not all follow the chapter order, and they require you to combine concepts and skills from several sections. These problems will help you increase your critical thinking skills and prepare for your next exam.
17.107 The insect repellent DEET can be made from an amidation reaction of 3 -methylbenzoic acid and diethylamine. Draw the line-angle formula for DEET. (17.7)Many insect repellents contain DEET, which is an amide. | ![]() |
Expert Solution & Answer
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Students have asked these similar questions
Don't used hand raiting and don't used Ai solution
13.84. Chlorine atoms react with methane, forming HCI
and CH3. The rate constant for the reaction is
6.0 × 107 M¹ s¹ at 298 K. When the experiment
was run at three other temperatures, the following data
were collected:
T (K)
k (M-1 s-1)
303
6.5 × 107
308
7.0 × 107
313
7.5 x 107
a. Calculate the values of the activation energy and the
frequency factor for the reaction.
b. What is the value of the rate constant in the lower
stratosphere, where T = 218 K?
My Organic Chemistry textbook says about the formation of cyclic hemiacetals, "Such intramolecular reactions to form five- and six-membered rings are faster than the corresponding intermolecular reactions. The two reacting functional groups, in this case OH and C=O, are held in close proximity, increasing the probability of reaction."According to the book, the formation of cyclic hemiacetals occurs in acidic conditions. So my question is whether the carbonyl group in this reaction reacts first with the end alcohol on the same molecule or with the ethylene glycol. And, given the explanation in the book, if it reacts first with ethylene glycol before its own end alcohol, why would it? I don't need to know the final answer. I need to know WHY it would not undergo an intermolecular reaction prior to reacting with the ethylene glycol if that is the case. Please do not use an AI answer.
Chapter 17 Solutions
Basic Chemistry
Ch. 17.1 - Prob. 1PPCh. 17.1 - Prob. 2PPCh. 17.1 - Prob. 3PPCh. 17.1 - Prob. 4PPCh. 17.1 - Prob. 5PPCh. 17.1 - Prob. 6PPCh. 17.1 - Prob. 7PPCh. 17.1 - Prob. 8PPCh. 17.1 - Prob. 9PPCh. 17.1 - Prob. 10PP
Ch. 17.1 - Prob. 11PPCh. 17.1 - Draw the condensed structural formula for each of...Ch. 17.1 - Prob. 13PPCh. 17.1 - Prob. 14PPCh. 17.1 - Prob. 15PPCh. 17.1 - Prob. 16PPCh. 17.1 - Prob. 17PPCh. 17.1 - Prob. 18PPCh. 17.2 - Prob. 19PPCh. 17.2 - Identify each of the following as an alkane,...Ch. 17.2 - Prob. 21PPCh. 17.2 - Prob. 22PPCh. 17.2 - Prob. 23PPCh. 17.2 - Prob. 24PPCh. 17.2 - Draw the condensed structural formula for the...Ch. 17.2 - Prob. 26PPCh. 17.2 - Prob. 27PPCh. 17.2 - Prob. 28PPCh. 17.2 - Prob. 29PPCh. 17.2 - Prob. 30PPCh. 17.2 - Prob. 31PPCh. 17.2 - Prob. 32PPCh. 17.3 - Prob. 33PPCh. 17.3 - Prob. 34PPCh. 17.3 - Prob. 35PPCh. 17.3 - Draw the line-angle formula for each of the...Ch. 17.4 - Prob. 37PPCh. 17.4 - Prob. 38PPCh. 17.4 - Prob. 39PPCh. 17.4 - Write the common name for each of the following:...Ch. 17.4 - Draw the condensed structural and line-angle...Ch. 17.4 - Draw the condensed structural and line-angle...Ch. 17.5 - Write the common name for each of the following:Ch. 17.5 - Write the common name for each of the following:Ch. 17.5 - Prob. 45PPCh. 17.5 - Prob. 46PPCh. 17.5 - Prob. 47PPCh. 17.5 - Draw the condensed structural formula for a and b...Ch. 17.6 - Prob. 49PPCh. 17.6 - Write the IUPAC and common name (if any) for each...Ch. 17.6 - Prob. 51PPCh. 17.6 - Prob. 52PPCh. 17.6 - Prob. 53PPCh. 17.6 - Prob. 54PPCh. 17.6 - Prob. 55PPCh. 17.6 - Prob. 56PPCh. 17.6 - Prob. 57PPCh. 17.6 - Write the IUPAC and common names, if any, for each...Ch. 17.6 - Draw the condensed structural formulas for a and b...Ch. 17.6 - Draw the condensed structural formulas for a and b...Ch. 17.7 - Write the common name for each of the following:...Ch. 17.7 - Prob. 62PPCh. 17.7 - Prob. 63PPCh. 17.7 - Prob. 64PPCh. 17.7 - Prob. 65PPCh. 17.7 - Prob. 66PPCh. 17.7 - Prob. 67PPCh. 17.7 - Prob. 68PPCh. 17.7 - Prob. 69PPCh. 17.7 - Prob. 70PPCh. 17.7 - Prob. 71PPCh. 17.7 - Prob. 72PPCh. 17 - The chapter sections to review are shown in...Ch. 17 - The chapter sections to review are shown in...Ch. 17 - Prob. 75UTCCh. 17 - Prob. 76UTCCh. 17 - Prob. 77APPCh. 17 - Prob. 78APPCh. 17 - Prob. 79APPCh. 17 - Prob. 80APPCh. 17 - Prob. 81APPCh. 17 - Prob. 82APPCh. 17 - Prob. 83APPCh. 17 - Prob. 84APPCh. 17 - Classify each of the following according to its...Ch. 17 - Classify each of the following according to its...Ch. 17 - Name each of the following aromatic compounds:...Ch. 17 - Prob. 88APPCh. 17 - Prob. 89APPCh. 17 - Draw the structural formula for each of the...Ch. 17 - Prob. 91APPCh. 17 - Prob. 92APPCh. 17 - Draw the condensed structural formula for each of...Ch. 17 - Draw the condensed structural formula for each of...Ch. 17 - Write the IUPAC name for each of the following:...Ch. 17 - Write the IUPAC name for each of the following:...Ch. 17 - Draw the condensed structural formulas for a and b...Ch. 17 - Prob. 98APPCh. 17 - Prob. 99APPCh. 17 - Prob. 100APPCh. 17 - Prob. 101APPCh. 17 - Draw the condensed structural formula for each of...Ch. 17 - Prob. 103APPCh. 17 - Prob. 104APPCh. 17 - Prob. 105CPCh. 17 - Prob. 106CPCh. 17 - The following problems are related to the topics...Ch. 17 - Prob. 108CPCh. 17 - The following problems are related to the topics...Ch. 17 - Prob. 110CP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Don't used hand raiting and don't used Ai solutionarrow_forwardHighlight in red each acidic location on the organic molecule at left. Highlight in blue each basic location on the organic molecule at right. Note for advanced students: we mean acidic or basic in the Brønsted-Lowry sense only. Cl N شیخ x Garrow_forwardQ4: Draw the mirror image of the following molecules. Are the molecules chiral? C/ F LL CI CH3 CI CH3 0 CI CH3 CI CH3 CH3arrow_forward
- Complete combustion of a 0.6250 g sample of the unknown crystal with excess O2 produced 1.8546 g of CO2 and 0.5243 g of H2O. A separate analysis of a 0.8500 g sample of the blue crystal was found to produce 0.0465 g NH3. The molar mass of the substance was found to be about 310 g/mol. What is the molecular formula of the unknown crystal?arrow_forward4. C6H100 5 I peak 3 2 PPM Integration values: 1.79ppm (2), 4.43ppm (1.33) Ipeakarrow_forwardNonearrow_forward
- 3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…arrow_forwardA chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.arrow_forwardNonearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningMacroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks ColeChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305580350/9781305580350_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577190/9781305577190_smallCoverImage.gif)
Macroscale and Microscale Organic Experiments
Chemistry
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Brooks Cole
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079243/9781305079243_smallCoverImage.gif)
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781133611097/9781133611097_smallCoverImage.gif)
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Lipids - Fatty Acids, Triglycerides, Phospholipids, Terpenes, Waxes, Eicosanoids; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=7dmoH5dAvpY;License: Standard YouTube License, CC-BY