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Concept explainers
(a)
Interpretation:
In the given acid‑base equilibria, the structure of missing substance has to be shown.
Concept Introduction:
Substituted ammonium ion is the one in which one or more alkyl, aryl, or cycloalkyl groups are substituted instead of hydrogen atoms. There are two important generalizations that is applied to the substituted ammonium ion and they are,
- Substituted ammonium ions are not neutral molecules. They are charged species.
- Nitrogen atom has four bonds in ammonium ion or substituted ammonium ion. The species is positively charged as the fourth bond formed is a coordinate covalent bond.
(b)
Interpretation:
In the given acid‑base equilibria, the structure of missing substance has to be shown.
Concept Introduction:
Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.
Substituted ammonium ion is the one in which one or more alkyl, aryl, or cycloalkyl groups are substituted instead of hydrogen atoms. There are two important generalizations that is applied to the substituted ammonium ion and they are,
- Substituted ammonium ions are not neutral molecules. They are charged species.
- Nitrogen atom has four bonds in ammonium ion or substituted ammonium ion. The species is positively charged as the fourth bond formed is a coordinate covalent bond.
(c)
Interpretation:
In the given acid‑base equilibria, the structure of missing substance has to be shown.
Concept Introduction:
Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.
Substituted ammonium ion is the one in which one or more alkyl, aryl, or cycloalkyl groups are substituted instead of hydrogen atoms. There are two important generalizations that is applied to the substituted ammonium ion and they are,
- Substituted ammonium ions are not neutral molecules. They are charged species.
- Nitrogen atom has four bonds in ammonium ion or substituted ammonium ion. The species is positively charged as the fourth bond formed is a coordinate covalent bond.
(d)
Interpretation:
In the given acid‑base equilibria, the structure of missing substance has to be shown.
Concept Introduction:
Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.
Substituted ammonium ion is the one in which one or more alkyl, aryl, or cycloalkyl groups are substituted instead of hydrogen atoms. There are two important generalizations that is applied to the substituted ammonium ion and they are,
- Substituted ammonium ions are not neutral molecules. They are charged species.
- Nitrogen atom has four bonds in ammonium ion or substituted ammonium ion. The species is positively charged as the fourth bond formed is a coordinate covalent bond.
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Chapter 17 Solutions
Bundle: General, Organic, and Biological Chemistry, 7th + OWLv2 Quick Prep for General Chemistry, 4 terms (24 months) Printed Access Card
- Suppose the rate of evaporation in a hot, dry region is 1.76 meters per year, and the seawater there has a salinity of 35 ‰. Assuming a 93% yield, how much salt (NaCl) can be harvested each year from 1 km2 of solar evaporation ponds that use this seawater as a source?arrow_forwardhelparrow_forwardExplain why only the lone pairs on the central atom are taken into consideration when predicting molecular shapearrow_forward
- (ME EX1) Prblm #9/10 Can you explain in detail (step by step) I'm so confused with these problems. For turmber 13 can u turn them into lewis dot structures so I can better understand because, and then as well explain the resonance structure part. Thanks for the help.arrow_forwardProblems 19 and 20: (ME EX1) Can you please explain the following in detail? I'm having trouble understanding them. Both problems are difficult for me to explain in detail, so please include the drawings and answers.arrow_forward(ME EX1) Prblm #4-11 Can you please help me and explain these I'm very confused in detail please. Prblm number 9 I don't understand at all (its soo confusing to me and redraw it so I can better depict it).arrow_forward
- ME EX1) Prblm #19-20 I'm so confused with these problems. Can you please help me solve them and explain them? Problems number 19-20, and thanks! step by step and in detail for me please helparrow_forwardCalculate the flux of oxygen between the ocean and the atmosphere, given that: Temp = 18°C Salinity = 35 ppt Density = 1025 kg/m3 Oxygen concentration measured in bulk water = 263.84 mmol/m3 Wind speed = 7.4 m/s Oxygen is observed to be about 10% initially supersaturatedarrow_forward( ME EX1) Prblm 27-28: Can you explain to me both prblms in detail and for prblm 28 what do you mean bi conjugated bi ponds and those structures I'm confused...arrow_forward
- A. Determine the number of electrons in a system of cyclic conjugation (zero if no cyclic conjugation). B. Specify whether the species is "a"-aromatic, "aa"-anti-aromatic, or "na"-non-aromatic (neither aromatic nor anti-aromatic). (Presume rings to be planar unless structure obviously prevents planarity. If there is more than one conjugated ring, count electrons in the largest.) 1. A.Electrons in a cyclic conjugated system. 18 B.The compound is (a, aa, or na) a 2. A.Electrons in a cyclic conjugated system. 10 B.The compound is (a, aa, or na) naarrow_forwardWater is boiling at 1 atm pressure in a stainless steel pan on an electric range. It is observed that 2 kg of liquid water evaporates in 30 min. Find the rate of heat transfer to the water (kW).arrow_forwardCould you please turn this into a complete Lewis dot structure formula for me so I can visualize it more clearly? and then do the explaining for the resonance structures that were given please.arrow_forward
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