The validation of the statement that at the limit of S as T → 0 the expression for entropy is k ln g 0 is to be stated. Concept introduction: Statistical thermodynamics is used to describe all possible configurations in a system at given physical quantities such as pressure, temperature and number of particles in the system. An important quantity in thermodynamics is the partition function that is represented as, q ≡ ∑ i g i e − β ∈ i It is also called as canonical ensemble partition function.

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Chapter 17, Problem 17.38E

Interpretation Introduction

Interpretation:

The validation of the statement that at the limit of S as T→0 the expression for entropy is klng0 is to be stated.

Concept introduction:

Statistical thermodynamics is used to describe all possible configurations in a system at given physical quantities such as pressure, temperature and number of particles in the system. An important quantity in thermodynamics is the partition function that is represented as,

q≡∑igie−β∈i

It is also called as canonical ensemble partition function.

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