PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 17, Problem 17.38E
Interpretation Introduction

Interpretation:

The validation of the statement that at the limit of S as T0 the expression for entropy is klng0 is to be stated.

Concept introduction:

Statistical thermodynamics is used to describe all possible configurations in a system at given physical quantities such as pressure, temperature and number of particles in the system. An important quantity in thermodynamics is the partition function that is represented as,

qigieβi

It is also called as canonical ensemble partition function.

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PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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