PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
expand_more
expand_more
format_list_bulleted
Question
Chapter 17, Problem 17.14E
Interpretation Introduction
Interpretation:
The state of the overall system for microcanonical ensemble is to be stated.
Concept introduction:
The thermodynamic state of a large microscopic system is understood using the statistical
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
In the water and nitrogen molecules, do they have the same electronic partition function? Explain it briefly
he lowest electronic levels for 14N 160 have the following characteristics: Calculate, for 5000 k, using statistics. A) The fraction of molecules
in the 3 electronic levels B) The partition functions for the 3 electronic levels Qti, Qvib, Qrot, and the total partition function. C) The energies
Eti, Evib, Etot, for the 3 electronic levels and the total energy and compare with the classical prediction. D) The fraction of molecules in the
state J = 2, V = 2 of the second electronic level. Eye /cm-1 Ge wavelength/cm-1 Radius
/10-10 0 2 1904.04 1.15077 43845.88 1 2374.31 1.0634 45793.78 2 1037.20 1.4167
10.
The 12C1O molecule has an equilibrium bond distance of 112.8 pm and a vibration frequency
of 2170 cm-'. Calculate:
1. The reduced mass and
2. The moment of inertia.
3. Force constant for vibration
4. The wavelength of the photon emitted when the molecule makes the transition from the J=1,
m=0 eigenstate to J=0; m=0 eigenstate and from J=2, m¡=0 eigenstate to J=0; m¡=0 eigenstate.
Chapter 17 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 17 - Prob. 17.1ECh. 17 - Prob. 17.2ECh. 17 - Prob. 17.3ECh. 17 - Prob. 17.4ECh. 17 - Prob. 17.5ECh. 17 - Prob. 17.6ECh. 17 - Prob. 17.7ECh. 17 - Prob. 17.8ECh. 17 - Prob. 17.9ECh. 17 - Prob. 17.10E
Ch. 17 - Prob. 17.11ECh. 17 - If the ni values are all the same, a shorthand way...Ch. 17 - Prob. 17.13ECh. 17 - Prob. 17.14ECh. 17 - Prob. 17.15ECh. 17 - Prob. 17.16ECh. 17 - Prob. 17.17ECh. 17 - Prob. 17.18ECh. 17 - Prob. 17.19ECh. 17 - Prob. 17.20ECh. 17 - Prob. 17.21ECh. 17 - Prob. 17.22ECh. 17 - Explain why q is a constant for a given system at...Ch. 17 - What is the ratio of ground-state nickel atoms in...Ch. 17 - Ti3+ has the following electronic energy levels:...Ch. 17 - Using the fact that =1/kT, show that equations...Ch. 17 - A one-dimensional particle-in-a-box has a length...Ch. 17 - Prob. 17.28ECh. 17 - Prob. 17.29ECh. 17 - Prob. 17.30ECh. 17 - Prob. 17.31ECh. 17 - What is the value of q at absolute zero? Is it the...Ch. 17 - Prob. 17.33ECh. 17 - Prob. 17.34ECh. 17 - Prob. 17.35ECh. 17 - Prob. 17.36ECh. 17 - Prob. 17.37ECh. 17 - Prob. 17.38ECh. 17 - Prob. 17.39ECh. 17 - Prob. 17.40ECh. 17 - Prob. 17.41ECh. 17 - Prob. 17.42ECh. 17 - What change is there in the Sackur-Tetrode...Ch. 17 - Prob. 17.44ECh. 17 - Prob. 17.45ECh. 17 - Prob. 17.46ECh. 17 - Calculate the thermal de Broglie wavelength of He...Ch. 17 - Prob. 17.48ECh. 17 - Prob. 17.49ECh. 17 - Prob. 17.50ECh. 17 - Prob. 17.51ECh. 17 - Prob. 17.52ECh. 17 - Prob. 17.53ECh. 17 - Use equation 17.56 to determine the change in...Ch. 17 - For an electron that has a velocity of 0.01c where...Ch. 17 - Use the Sackur-Tetrode equation to derive the...Ch. 17 - Prob. 17.57ECh. 17 - Prob. 17.58E
Knowledge Booster
Similar questions
- Calculate the vibrational and rotational contributions (with zero point energy) to the molar Gibbs energy of a frozen solid form of carbon dioxide at 200 K. Vibrational frequencies are the following: singly degenerate 1388.2 cm-1 and 667.4 cm-1, and doubly degenerate 2349.2cm-1 . The rotational constant is 0.3902 cm-1. Please type answer not write by hendarrow_forwardDetermine urms, <u>, ump, and <ur> for a collection of chlorine molecules at 300K.arrow_forward1. Show that the partition function for a harmonic oscillator in the x direction only is given by: 9x exp(-ẞhy) 1-exp(-ẞhv) 2. Using your answer to part (1), derive the partition function for a single harmonic oscillator in three different directions. Briefly note any assumptions made. 3. Using your answer to part (2), show that the partition function for a crystal of n atoms (i.e., a collection of harmonic oscillators in three different directions) is given by: 3N exp(-ẞhv) Qays 1-exp(-ẞhv)arrow_forward
- Solve question 1,2,3 and 4arrow_forwardI need the answer as soon as possiblearrow_forward2. The following is the relative number of molecules in the vibrational states of the 1CI molecule determined from spectroscopy: Vibrational level E, E, E, E, E, E, Relative Population 100 53.5 28.6 15.3 8.2 4.4 Calculate the temperature of the sample given that the vibrational frequency is 1.15 x 10"s'.arrow_forward
- Two points that lie on the line of best fit for a ln k versus 1/T graph are (0.00412, -1.34) and (0.00649, -4.99). What is the natural log of the frequency factor (ln A)?arrow_forwardPlease complete all the following parts of the question thank you and provide reasonings and which equations and why were they used. THANK YOUarrow_forwardPhysical and analytical applications of vibration spectra.arrow_forward
- 1arrow_forwardFor all three of your assigned systems (Ne, Oxygen, Nitrous oxide), calculate the complete partition function (assuming a perfect gas) at T, = 2.00 and e, = 0.0500. Information on the symmetry number for your polyatomic molecules is posted in a table under the Reference section in the Content Library The symmetry number for rotational partition functions. Homonuclear diatomics: o=2 Heteronuclear diatomics: o=1 Polyatomics: Name Nitrous oxide 1arrow_forwardThe GeF molecule, which exists in the gas phase at high temperature, has a 2 electronic ground state. What are the term symbols of the electronic states that can be accessed by allowed electronic transitions?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning