PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 17, Problem 17.36E
Interpretation Introduction

(a)

Interpretation:

The second-law spontaneity is to be justified for the given situation using statistical thermodynamic arguments.

Concept introduction:

The second law of thermodynamics states that for an isolated system, that is, a system in which there is no transfer of matter or energy, the entropy of the system always increases with time.

Interpretation Introduction

(b)

Interpretation:

The second-law spontaneity is to be justified for the given situation using statistical thermodynamic arguments.

Concept introduction:

The second law of thermodynamics states that for an isolated system, that is, a system in which there is no transfer of matter or energy, the entropy of the system always increases with time.

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Assume N₂ behaves as perfect gas. It expands reversibly and adiabatically from Vi to Vf with the pressure change from pi to pf. (a) Derive the temperature versus volume relationship and the pressure and volume relationship for this expansion. (b) When a sample of N₂ of mass 3.12 g at 23.0 °C is allowed to expand reversibly and adiabatically from 4.00 × 10² cm3 to 2.00 dm3, what is the work done by the gas?
A sample of 4.50 g of methane occupies 12.7 dm³ at 310 K. (a) Calculate the work done when the gas expands isothermally against a constant external pressure of 200 Torr until its volume has increased by 3.3 dm³. (b) Calculate the work that would be done if the same expansion occurred reversibly.
One mole of N2(g) occupies 5 L of volume at 300 K in a sealed cylinder. The gas behaves ideally in expanding isothermally to 10 L. Calculate w, ΔE and ΔH if the expansion proceeds (i) reversibly, (ii) irreversibly against an external pressure at 0.2 atm.

Chapter 17 Solutions

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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