PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 17, Problem 17.37E
Interpretation Introduction

Interpretation:

The explanation of the fact that equation 17.44 and 17.45 for A and G differ only by the +1 term only is to be stated.

Concept introduction:

Gibbs free energy gives the value of the maximum reversible amount of work done by system at a condition of constant temperature and pressure. It is a state function.

Helmholtz energy gives the value of the maximum amount of work done by system at a condition of constant volume. It is a state function.

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An experiment involving inorganic syntheses of molecular precursors to organometallic ceramics requires reactions that involve the formation of a metal-metal bond. The percentage of such a bond forming is p=20% If X is the number of successful reactions out of 25 such experiments; a)       what is the minimum number of successful reactions are formed if 58% of them form the metal-metal bond? b)      what is the probability of having the third successful reaction on the 5th experiment? c)       What is the probability that the successful bond is formed for the first time on the 3th experiment?
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Chapter 17 Solutions

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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