PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 17, Problem 17.33E
Interpretation Introduction

Interpretation:

The equation 17.42 is to be derived using equation 17.41 by following the steps outlined in the text.

Concept introduction:

Statistical thermodynamics is used to describe all possible configurations in a system at given physical quantities such as pressure, temperature and number of particles in the system. The important quantity in thermodynamics is partition function that is represented as,

qigieβi

It is also called as canonical ensemble partition function.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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