Consider a salt bridge voltaic cell represented by the following reaction MnO 4 − ( a q ) + 8 H + ( a q ) + 5 Fe 2 + ( a q ) → Mn 2 + ( a q ) + 5 Fe 3 + ( a q ) + 4 H 2 O (a) What is the direction of the electrons in the external circuit? (b) What electrode can be used at the anode? (c) What is the reaction occurring at the cathode?
Consider a salt bridge voltaic cell represented by the following reaction MnO 4 − ( a q ) + 8 H + ( a q ) + 5 Fe 2 + ( a q ) → Mn 2 + ( a q ) + 5 Fe 3 + ( a q ) + 4 H 2 O (a) What is the direction of the electrons in the external circuit? (b) What electrode can be used at the anode? (c) What is the reaction occurring at the cathode?
Solution Summary: The author explains how electrons travel through the external circuit to reach the cathode. In a voltaic salt bridge cell, oxidation and reduction take place at anodes.
Consider a salt bridge voltaic cell represented by the following reaction
MnO
4
−
(
a
q
)
+
8
H
+
(
a
q
)
+
5
Fe
2
+
(
a
q
)
→
Mn
2
+
(
a
q
)
+
5
Fe
3
+
(
a
q
)
+
4
H
2
O
(a) What is the direction of the electrons in the external circuit? (b) What electrode can be used at the anode? (c) What is the reaction occurring at the cathode?
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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Np, N₁ = 82,126
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protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
5.
Please consider the Newman projection of tartaric acid drawn below as an eclipsed
conformer (1). Please draw the most stable conformer and two intermediate energy conformers
noting that staggered conformers are lower in energy than eclipsed forms even if the staggered
conformers have gauche relationships between groups. [Draw the substituents H and OH on the front
carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.]
OH
COH
ICOOH
COOH
COOH
1
2
COOH
COOH
3
4
Staggered
Staggered
Staggered (most stable)
Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies
below.
Ref=0
Rotation
6. (60 points)
a. Are compounds 1 and 2 below enantiomers, diastereomers or identical?
OH
OH
HO
HO
LOH
HO
HO
OH
2
OH
OH
b. Please complete the zig-zag conformation of the compound
(3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes.
3.
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