(a)
Interpretation:
The number of electrons during the
Concept introduction:
(b)
Interpretation:
The number of coulombs during electrolysis process needs to be calculated.
Concept introduction:
Faraday’s constant (F) is defined as charge in Coulomb of 1 mole electron.
Value of Faraday’s constant can be calculated by multiplying charge of one electron with Avogadro’s number.
(c)
Interpretation:
The mass of
Concept introduction:
Formula to calculate mass is as follows:
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Chapter 17 Solutions
Chemistry: Principles and Reactions
- When molten lithium chloride, LiCl, is electrolyzed, lithium metal is liberated at the cathode. How many grams of lithium are liberated when 2.00 103 C of charge passes through the cell?arrow_forwardConsider the following cell running under standard conditions: Fe(s)Fe2+(aq)Al3+(aq)Al(s) a Is this a voltaic cell? b Which species is being reduced during the chemical reaction? c Which species is the oxidizing agent? d What happens to the concentration of Fe3+(aq) as the reaction proceeds? e How does the mass of Al(s) change as the reaction proceeds?arrow_forwardAn electrode is prepared from liquid mercury in contact with a saturated solution of mercury(I) chloride, Hg2Cl, containing 1.00 M Cl . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.268 V. What is the solubility product of mercury(I) chloride?arrow_forward
- Write balanced net ionic equations for the following reactions in acid solution. (a) Liquid hydrazine reacts with an aqueous solution of sodium bromate. Nitrogen gas and bromide ions are formed. (b) Solid phosphorus (P4) reacts with an aqueous solution of nitrate to form nitrogen oxide gas and dihydrogen phosphate (H2PO4-) ions. (c) Aqueous solutions of potassium sulfite and potassium permanganate react. Sulfate and manganese(II) ions are formed.arrow_forwardAn electrolytic cell is set up with Cd(s) in Cd(NO3)2(aq) and Zn(s) in Zn(NO3)2(aq). Initially both electrodesweigh 5.00 g. After running the cell for several hours theelectrode in the left compartment weighs 4.75 g. (a) Which electrode is in the left compartment? (b) Does the mass of the electrode in the right compartmentincrease, decrease, or stay the same? If the masschanges, what is the new mass? (c) Does the volume of the electrode in the right compartment increase, decrease, or stay the same? If the volumechanges, what is the new volume? (The density of Cd is8.65 g/cm3.)arrow_forwardOrder the following oxidizing agents by increasing strength under standard-state conditions: Mg2+(aq), Hg2+(aq), Pb2+(aq).arrow_forward
- The iron content of hemoglobin is determined by destroying the hemoglobin molecule and producing small water-soluble ions and molecules. The iron in the aqueous solution is reduced to iron(II) ion and then titrated against potassium permanganate. In the titration, iron(ll) is oxidized to iron(III) and permanganate is reduced to manganese(II) ion. A 5.00-g sample of hemoglobin requires 32.3 mL of a 0.002100 M solution of potassium permanganate. The reaction with permanganate ion is MnO4(aq)+8H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+(aq)+4H2O What is the mass percent of iron in hemoglobin?arrow_forwardCalcium metal can be obtained by the direct electrolysis of molten CaCl2, at a voltage of 3.2 V. (a) How many joules of electrical energy are required to obtain 12.0 1b of calcium? (b) What is the cost of the electrical energy obtained in (a) if electrical energy is sold at the rate of nine cents per kilowatt hour?arrow_forwardAn aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forward
- A solution of copper(II) sulfate is electrolyzed by passing a current through the solution using inert electrodes. Consequently, there is a decrease in the Cu2+ concentration and an increase in the hydronium ion concentration. Also, one electrode increases in mass and a gas evolves at the other electrode. Write half-reactions that occur at the anode and at the cathode.arrow_forwardDescribe what you expect to happen when the following solutions are electrolyzed: a aqueous Na2SO4; b aqueous KBr. That is, what are the electrode reactions? What is the overall reaction?arrow_forwardAssign an oxidation number to the underlined atom in each ion or molecule. (a) Fe2O3, (b) H2SO4, (C) CO32- (C) NO2+arrow_forward
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