How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown. Concept introduction: Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO 4 will yield the acid required. To show: How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

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Answer 1

Question

Chapter 16.SE, Problem 26VC

Interpretation Introduction

Interpretation:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown.

Concept introduction:

Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO₄ will yield the acid required.

To show:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

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Answer 2

Question

Chapter 16.SE, Problem 26VC

Interpretation Introduction

Interpretation:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown.

Concept introduction:

Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO₄ will yield the acid required.

To show:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 16.SE, Problem 26VC

Interpretation Introduction

Interpretation:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown.

Concept introduction:

Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO₄ will yield the acid required.

To show:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 16.SE, Problem 26VC

Interpretation Introduction

Interpretation:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown.

Concept introduction:

Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO₄ will yield the acid required.

To show:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 16.SE, Problem 26VC

Interpretation Introduction

Interpretation:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown.

Concept introduction:

Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO₄ will yield the acid required.

To show:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

Answer 6

Chapter 16.SE, Problem 26VC

Interpretation Introduction

Interpretation:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown.

Concept introduction:

Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO₄ will yield the acid required.

To show:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

Answer 7

Chapter 16.SE, Problem 26VC

Interpretation Introduction

Interpretation:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene is to be shown.

Concept introduction:

Benzene can be converted into alkyl benzenes by the Friedal-Crafts alkylation reaction. The alkyl group when nitrated directs the nitro group into ortho & para positions to yield nitroalkylbenzenes. The para isomer is favored as it is strain free. Oxidation of the alkyl group in the nitro alkyl benzene with KMnO₄ will yield the acid required.

To show:

How the compound shown (p-aminobenzoic acid) can be synthesized from benzene

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 16.1 - Prob. 1P Ch. 16.2 - Propose a mechanism for the electrophilic...Ch. 16.2 - How many products might be formed on chlorination...Ch. 16.2 - When benzene is treated with D2SÅª4. deuterium...Ch. 16.3 - Prob. 5P Ch. 16.3 - What is the major monosubstitution product from...Ch. 16.3 - Identify the carboxylic acid chloride that might...Ch. 16.4 - Rank the compounds in each of the following groups...Ch. 16.4 - Predict the major products of the following...Ch. 16.4 - Prob. 10P

Solution Summary: The author explains how p-aminobenzoic acid can be synthesized from benzene through the steps shown below.

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Chapter 16 Solutions