Given that monobromination of toluene gives a mixture of three bromotoluenes as products. Their structures are to be drawn and their names are to be given. Concept introduction: When a monosubstituted benzene undergoes electrophilic substitution reaction, the second electrophile can enter into either ortho or para or meta position. Normally depending upon the nature of the substituent group already present the ortho and para isomers or the meta isomer is obtained as the major product. To draw: The structures of three monobromotoluenes obtained by monobromination of toluenes.

Question

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Answer 1

Question

Chapter 16.1, Problem 1P

Interpretation Introduction

Interpretation:

Given that monobromination of toluene gives a mixture of three bromotoluenes as products. Their structures are to be drawn and their names are to be given.

Concept introduction:

When a monosubstituted benzene undergoes electrophilic substitution reaction, the second electrophile can enter into either ortho or para or meta position. Normally depending upon the nature of the substituent group already present the ortho and para isomers or the meta isomer is obtained as the major product.

To draw:

The structures of three monobromotoluenes obtained by monobromination of toluenes.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH