Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 16, Problem 82QRT
The molecular structure shown is of one form of glucose,
C6H12O6
Glucose can be oxidized to carbon dioxide and water according to the equation
C6H12O6(S) + 6 O2(g)→6 CO2(g) + 6 H2O(g)
- (a) Using the method described in Section 6-6a for estimating enthalpy changes from bond energies, estimate ΔrH° for the oxidation of this form of glucose. Make a list of all bonds broken and all bonds formed in this process.
- (b) Compare your result with the experimental value of– 2816 kJ/mol for combustion of glucose. Why might there be a difference between this value and the one you calculated in part (a)?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Show work..don't give Ai generated solution
Show work..don't give Ai generated solution
Pheromone G of the maize stalk borer, chilo partelus, can be synthesized based on the partial scheme shown below. Complete the scheme by identifying the structures of the intermediate compounds A, B, C, D, E, F and pheromone G. Indicate stereochemistry where relevant
Chapter 16 Solutions
Chemistry: The Molecular Science
Ch. 16.1 - Write a chemical equation for each process and...Ch. 16.2 - Prob. 16.2CECh. 16.3 - A chemical reaction transfers 30.8 kJ to a thermal...Ch. 16.3 - Prob. 16.3CECh. 16.3 - Prob. 16.2PSPCh. 16.3 - For each process, predict whether entropy...Ch. 16.4 - Calculate the entropy change for each of these...Ch. 16.5 - The reaction of carbon monoxide with hydrogen to...Ch. 16.5 - Prob. 16.4PSPCh. 16.5 - Prob. 16.6CE
Ch. 16.5 - Prob. 16.8ECh. 16.6 - Prob. 16.9CECh. 16.6 - In the text we concluded that the reaction to...Ch. 16.6 - Prob. 16.10CECh. 16.6 - Prob. 16.6PSPCh. 16.7 - Prob. 16.7PSPCh. 16.7 - Prob. 16.8PSPCh. 16.7 - Prob. 16.9PSPCh. 16.8 - Predict whether each reaction is reactant-favored...Ch. 16.9 - Prob. 16.13ECh. 16.9 - Prob. 16.11PSPCh. 16.9 - Prob. 16.12PSPCh. 16.9 - Prob. 16.14ECh. 16.11 - All of these substances are stable with respect to...Ch. 16 - Define the terms product-favored System and...Ch. 16 - What are the two ways that a final chemical state...Ch. 16 - Define the term entropy, and give an example of a...Ch. 16 - Prob. 4QRTCh. 16 - Prob. 5QRTCh. 16 - Prob. 6QRTCh. 16 - Prob. 7QRTCh. 16 - Prob. 8QRTCh. 16 - Prob. 9QRTCh. 16 - Prob. 10QRTCh. 16 - Prob. 11QRTCh. 16 - Prob. 12QRTCh. 16 - Prob. 13QRTCh. 16 - Prob. 14QRTCh. 16 - Prob. 15QRTCh. 16 - Prob. 16QRTCh. 16 - Prob. 17QRTCh. 16 - Suppose you have four identical molecules labeled...Ch. 16 - For each process, tell whether the entropy change...Ch. 16 - Prob. 20QRTCh. 16 - For each situation described in Question 13,...Ch. 16 - Prob. 22QRTCh. 16 - Prob. 23QRTCh. 16 - Prob. 24QRTCh. 16 - Prob. 25QRTCh. 16 - Prob. 26QRTCh. 16 - Prob. 27QRTCh. 16 - Prob. 28QRTCh. 16 - Prob. 29QRTCh. 16 - Prob. 30QRTCh. 16 - Prob. 31QRTCh. 16 - Diethyl ether, (C2H5)2O, was once used as an...Ch. 16 - Calculate rS for each substance when the quantity...Ch. 16 - Prob. 34QRTCh. 16 - Prob. 35QRTCh. 16 - Check your predictions in Question 28 by...Ch. 16 - Prob. 37QRTCh. 16 - Prob. 38QRTCh. 16 - Prob. 39QRTCh. 16 - Prob. 40QRTCh. 16 - Prob. 41QRTCh. 16 - Prob. 42QRTCh. 16 - Prob. 43QRTCh. 16 - Prob. 44QRTCh. 16 - Prob. 45QRTCh. 16 - Prob. 46QRTCh. 16 - Hydrogen bums in air with considerable heat...Ch. 16 - Prob. 48QRTCh. 16 - Prob. 49QRTCh. 16 - Prob. 50QRTCh. 16 - Prob. 51QRTCh. 16 - The reaction of magnesium with water can be used...Ch. 16 - Prob. 53QRTCh. 16 - Prob. 54QRTCh. 16 - Prob. 55QRTCh. 16 - Prob. 56QRTCh. 16 - Prob. 57QRTCh. 16 - Prob. 58QRTCh. 16 - Prob. 59QRTCh. 16 - Prob. 60QRTCh. 16 - Prob. 61QRTCh. 16 - Estimate ΔrG° at 2000. K for each reaction in...Ch. 16 - Prob. 63QRTCh. 16 - Some metal oxides, such as lead(II) oxide, can be...Ch. 16 - Prob. 65QRTCh. 16 - Prob. 66QRTCh. 16 - Use data from Appendix J to obtain the equilibrium...Ch. 16 - Prob. 68QRTCh. 16 - Prob. 69QRTCh. 16 - Use the data in Appendix J to calculate rG andKPat...Ch. 16 - Prob. 71QRTCh. 16 - Prob. 72QRTCh. 16 - Prob. 73QRTCh. 16 - Prob. 74QRTCh. 16 - Prob. 75QRTCh. 16 - Prob. 76QRTCh. 16 - Prob. 77QRTCh. 16 - Prob. 78QRTCh. 16 - Prob. 79QRTCh. 16 - The molecular structure shown is of one form of...Ch. 16 - Another step in the metabolism of glucose, which...Ch. 16 - In muscle cells under the condition of vigorous...Ch. 16 - The biological oxidation of ethanol, C2H5OH, is...Ch. 16 - Prob. 86QRTCh. 16 - For one day, keep a log of all the activities you...Ch. 16 - Billions of pounds of acetic acid are made each...Ch. 16 - Determine the standard Gibbs free energy change,...Ch. 16 - There are millions of organic compounds known, and...Ch. 16 - Actually, the carbon in CO2(g) is...Ch. 16 - The standard molar entropy of methanol vapor,...Ch. 16 - The standard molar entropy of iodine vapor, I2(g),...Ch. 16 - Prob. 94QRTCh. 16 - Prob. 96QRTCh. 16 - Prob. 97QRTCh. 16 - Prob. 98QRTCh. 16 - Prob. 99QRTCh. 16 - Prob. 100QRTCh. 16 - Appendix J lists standard molar entropies S, not...Ch. 16 - When calculating rSfromSvalues, it is necessary to...Ch. 16 - Prob. 103QRTCh. 16 - Explain how the entropy of the universe increases...Ch. 16 - Prob. 105QRTCh. 16 - Prob. 106QRTCh. 16 - Prob. 107QRTCh. 16 - Prob. 108QRTCh. 16 - Prob. 109QRTCh. 16 - Reword the statement in Question 109 so that it is...Ch. 16 - Prob. 111QRTCh. 16 - Prob. 112QRTCh. 16 - Prob. 113QRTCh. 16 - Prob. 114QRTCh. 16 - Prob. 115QRTCh. 16 - Prob. 116QRTCh. 16 - From data in Appendix J, estimate (a) the boiling...Ch. 16 - Prob. 118QRTCh. 16 - Prob. 119QRTCh. 16 - Prob. 120QRTCh. 16 - Prob. 121QRTCh. 16 - Prob. 122QRTCh. 16 - Prob. 123QRTCh. 16 - Prob. 124QRTCh. 16 - Prob. 125QRTCh. 16 - Prob. 126QRTCh. 16 - The standard equilibrium constant is 2.1109for...Ch. 16 - Prob. 16.ACPCh. 16 - Prob. 16.CCPCh. 16 - Prob. 16.DCPCh. 16 - Consider planet Earth as a thermodynamic system....
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Q8: Draw the resonance structures for the following molecule. Show the curved arrows (how you derive each resonance structure). Circle the major resonance contributor. одarrow_forwardQ9: Explain why compound I is protonated on O while compound II is protonated on N. NH2 DD I II NH2arrow_forwardComplete the following reaction by identifying the principle organic product of the reactionarrow_forward
- Denote the dipole for the indicated bonds in the following molecules. ✓ H3C CH3 B F-CCl3 Br-Cl H3C —Si(CH3)3 CH3 OH HO HO H HO OH vitamin Carrow_forward(a) What is the hybridization of the carbon in the methyl cation (CH3*) and in the methyl anion (CH3)? (b) What is the approximate H-C-H bond angle in the methyl cation and in the methyl anion?arrow_forward10:16 ☑ Vo)) Vo) 4G LTE 76% Complete the following reaction by identifying the principle organic product of the reaction. HO OH ↑ CH2N2 OH ? ○ A. 01 N₂H2C OH ОН B. HO OCH3 OH ○ C. HO OH ŎCH₂N2 ○ D. H3CO OH он Quiz navigation 1 2 3 4 5 11 12 Next page 10 6 7 8 9 10arrow_forward
- Which one of the following statements explain why protecting groups are referred to as “a necessary evil in organic synthesis”? Question 12Select one or more: A. They increase the length and cost of the synthesis B. Every synthesis employs protecting groups C. Protecting group have no role to play in a synthesis D. They minimize the formation of side productsarrow_forwardWhich of the following attributes is a key advantage of the chiral auxiliary approach over the chiral pool approach in asymmetric synthesis? Question 10Select one: A. Chiral auxiliaries are cheaper than chiral pool substrates B. Chiral auxiliary can be recovered and recycled unlike chiral pool substrates. C. The use of chiral auxiliaries provide enantiopure products, while chiral pool reactions are only enantioselective D. The chiral auxiliaries are naturally occurring and do not require synthesisarrow_forwardIn the following molecule, indicate the hybridization and shape of the indicated atoms. CH3 CH3 H3C HO: CI:arrow_forward
- Which of the following are TRUE about linear syntheses? Question 7Select one: A. They are easier to execute B. They are the most efficient strategy for all syntheses C. They are generally shorter than convergent syntheses D. They are less versatile compared to convergent synthesesarrow_forwardWhich of the following characteristics is common among chiral pool substrates? Question 4Select one: A. They have good leaving groups B. They are all achiral C. All have a multiplicity of chiral centres D. They have poor leaving groupsarrow_forwardDetermine whether the following reaction is an example of a nucleophilic substitution reaction: H NO2 H+ NO 2 + Molecule A Molecule B Is this a nucleophilic substitution reaction? If this is a nucleophilic substitution reaction, answer the remaining questions in this table. What word or two-word phrase is used to describe the role Molecule A plays in this reaction? What word or two-word phrase is used to describe the role Molecule B plays in this reaction? Use a 6 + symbol to label the electrophilic carbon that is attacked during the substitution. Highlight the leaving group on the appropriate reactant. O Yes ○ No ☐ 0 dx 000 HE ?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY