The value of Δ r S universe has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted. Concept Introduction: If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

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Answer 1

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 2

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

Answer 7

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16.1 - Write a chemical equation for each process and...Ch. 16.2 - Prob. 16.2CE Ch. 16.3 - A chemical reaction transfers 30.8 kJ to a thermal...Ch. 16.3 - Prob. 16.3CE Ch. 16.3 - Prob. 16.2PSP Ch. 16.3 - For each process, predict whether entropy...Ch. 16.4 - Calculate the entropy change for each of these...Ch. 16.5 - The reaction of carbon monoxide with hydrogen to...Ch. 16.5 - Prob. 16.4PSP Ch. 16.5 - Prob. 16.6CE

Solution Summary: The author explains that if the entropy change for the universe is positive, then the reaction will be spontaneous or product favored.

Videos

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

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Chapter 16 Solutions

Solution Summary: The author explains that if the entropy change for the universe is positive, then the reaction will be spontaneous or product favored.

Videos

Interpretation: The value of ΔrG° has to be calculated and the result of part (a) has to be verified. Concept Introduction: Refer to part (a).

Interpretation: Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted. Concept Introduction: Refer to part (a).

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Chapter 16 Solutions

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).