The value of Δ r S universe has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted. Concept Introduction: If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

Question

Want to see the full answer?

Answer 1

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

with full details solution please

Answer 2

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

Answer 7

Chapter 16, Problem 51QRT

(a)

Interpretation Introduction

Interpretation:

The value of ΔrSuniverse has to be calculated and on the basis of this value, whether the reaction is product favored at 25 °C has to be predicted.

Concept Introduction:

If the entropy change for the universe is positive, then the reaction will be spontaneous or product favored. The Gibbs free energy of a system is defined as the Gibbs free energy of product minus Gibbs free energy of reactants. The Gibbs free energy of the system is a state function as it is defined in terms of thermodynamic properties that are state functions.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 16.1 - Write a chemical equation for each process and...Ch. 16.2 - Prob. 16.2CE Ch. 16.3 - A chemical reaction transfers 30.8 kJ to a thermal...Ch. 16.3 - Prob. 16.3CE Ch. 16.3 - Prob. 16.2PSP Ch. 16.3 - For each process, predict whether entropy...Ch. 16.4 - Calculate the entropy change for each of these...Ch. 16.5 - The reaction of carbon monoxide with hydrogen to...Ch. 16.5 - Prob. 16.4PSP Ch. 16.5 - Prob. 16.6CE

Solution Summary: The author explains that if the entropy change for the universe is positive, then the reaction will be spontaneous or product favored.

Videos

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).

Want to see the full answer?

Chapter 16 Solutions

Solution Summary: The author explains that if the entropy change for the universe is positive, then the reaction will be spontaneous or product favored.

Videos

Interpretation: The value of ΔrG° has to be calculated and the result of part (a) has to be verified. Concept Introduction: Refer to part (a).

Interpretation: Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted. Concept Introduction: Refer to part (a).

Want to see the full answer?

Chapter 16 Solutions

Interpretation:

The value of ΔrG° has to be calculated and the result of part (a) has to be verified.

Concept Introduction:

Refer to part (a).

Interpretation:

Whether the calculation in part (a) and part (b) agree with the preconceived idea of this reaction has to be predicted.

Concept Introduction:

Refer to part (a).