(a) Interpretation: The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated. Concept introduction: The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

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Answer 1

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 2

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 3

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 4

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 5

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 6

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 7

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author analyzes the ranking of compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction.

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