(a) Interpretation: The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated. Concept introduction: The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow. The organic reaction in which substitution of an aromatic compound , in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

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Answer 1

Question

Chapter 16, Problem 16.15P

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexanol is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiCl

Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOH

Answer 2

Question

Chapter 16, Problem 16.15P

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexanol is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

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Answer 3

Question

Chapter 16, Problem 16.15P

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexanol is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

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Answer 4

Question

Chapter 16, Problem 16.15P

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexanol is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

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Answer 5

Chapter 16, Problem 16.15P

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexanol is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Answer 6

Chapter 16, Problem 16.15P

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Answer 7

Chapter 16, Problem 16.15P

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexene is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexanol is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the reaction between benzene and cyclohexanol is to be stated.

Concept introduction:

The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow.

The organic reaction in which substitution of an aromatic compound, in the presence of strong Lewis acid, takes place with the alkyl group is known as Friedel-Crafts alkylation.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains the curved arrow mechanism for the reaction between benzene and cyclohexanol.

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