Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 16, Problem 16.19P
Interpretation Introduction

Interpretation:

Two different methods to prepare the given compound with the help of Friedel-crafts reaction is to be stated.

Concept introduction:

The reaction between acyl chloride with benzene in presence of AlCl3 is a friedal craft acylation reaction. In friedal craft acylation reaction, AlCl3 acts as a lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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First image: Why can't the molecule C be formed in those conditions  Second image: Synthesis for lactone C its not an exam
First image: I have to show the mecanism for the reaction on the left, where the alcohol A is added fast in one portion Second image: I have to show the mecanism of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary
First image: I have to explain why the molecule C is never formed in those conditions. Second image: I have to propose a synthesis for the lactone A

Chapter 16 Solutions

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