Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Textbook Question
Chapter 15.1, Problem 15.1CE
Predict whether 1.0 L of each solution is a buffer: (a) equal amounts (mol) of HCl and NaCl; (b) equal amounts (mol) of KOH and KCl. Explain each prediction.
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How many moles of NH4Cl must be added to 2.0 L of 0.10 M NH3 to form a buffer whose pH is 9.00? (Assume that the addition of NH4Cl does not change the volume of the solution.)
6. Which of the following mixtures would create an effective buffer?
Give your reasoning in each case.
a) 0.10 mol HCl and 0.10 mol NaOH in 1.0L H₂O.
b) 0.10 mol NH3 and 0.15mol NH4Cl in 1.0L H₂O.
c) 0.010mol HCN and 0.20mol NaCN 1.0L H₂O.
d) 0.10 mol NH4Cl and 0.20mol NaCN in 1.0L H₂O.
e) 0.10 mol HCl and 0.20mol NaCN 1.0L H₂O.
suppose that the ph of buffer A turned out at ph 5.5 instead of ph 5.0 (100.0 mL of a 0.5 M buffer) which chemical (hcl or NaOH) would need to be added to adjust this error? how much moles of this chemical would need to be added?
Chapter 15 Solutions
Chemistry: The Molecular Science
Ch. 15.1 - Predict whether 1.0 L of each solution is a...Ch. 15.1 - Calculate the pH of blood containing 0.0020-M...Ch. 15.1 - Prob. 15.2ECh. 15.1 -
Calculate the ratio of [] to [] in blood at a...Ch. 15.1 - Use the data in Table 15.1 to select a conjugate...Ch. 15.1 -
Calculate the mole ratio of sodium acetate and...Ch. 15.1 - Calculate the pH of these buffers.
Ch. 15.1 - If an abnormally high CO2 concentration is present...Ch. 15.1 - Calculate the minimum mass (g) of KOH that would...Ch. 15.2 - For the titration of 50.0 mL of 0.100-M HCl with...
Ch. 15.2 - Draw the titration curve for the titration of 50.0...Ch. 15.2 - Use the Ka expression and value for acetic acid to...Ch. 15.2 - Explain why the curve for the titration of acetic...Ch. 15.4 - Write the Ksp expression for each of these...Ch. 15.4 - The Ksp of AgBr at 100 C is 5 1010. Calculate the...Ch. 15.4 - A saturated solution of silver oxalate. Ag2C2O4....Ch. 15.4 - Prob. 15.9CECh. 15.5 - Consider 0.0010-M solutions of these sparingly...Ch. 15.5 - Prob. 15.11PSPCh. 15.5 - Calculate the solubility of PbCl2 in (a) pure...Ch. 15.5 - Prob. 15.13PSPCh. 15.6 - (a) Determine whether AgCl precipitates from a...Ch. 15.6 - Prob. 15.15PSPCh. 15 - Prob. 1SPCh. 15 - Choose a weak-acid/weak-base conjugate pair from...Ch. 15 - Prob. 4SPCh. 15 - Define the term buffer capacity.Ch. 15 - What is the difference between the end point and...Ch. 15 - What are the characteristics of a good acid-base...Ch. 15 - A strong acid is titrated with a strong base, such...Ch. 15 - Repeat the description for Question 4, but use a...Ch. 15 - Use Le Chatelier’s principle to explain why PbCl2...Ch. 15 - Describe what a complex ion is and give an...Ch. 15 - Define the term “amphoteric”.
Ch. 15 - Distinguish between the ion product (Q) expression...Ch. 15 - Describe at least two ways that the solubility of...Ch. 15 - Briefly describe how a buffer solution can control...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Many natural processes can be studied in the...Ch. 15 - Which of these combinations is the best to buffer...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Calculate the mass of sodium acetate, NaCH3COO,...Ch. 15 - Calculate the mass in grams of ammonium chloride,...Ch. 15 - A buffer solution can be made from benzoic acid,...Ch. 15 - A buffer solution is prepared from 5.15 g NH4NO3...Ch. 15 - You dissolve 0.425 g NaOH in 2.00 L of a solution...Ch. 15 - A buffer solution is prepared by adding 0.125 mol...Ch. 15 - If added to 1 L of 0.20-M acetic acid, CH3COOH,...Ch. 15 - If added to 1 L of 0.20-M NaOH, which of these...Ch. 15 - Calculate the pH change when 10.0 mL of 0.100-M...Ch. 15 - Prob. 29QRTCh. 15 - Prob. 30QRTCh. 15 - Prob. 31QRTCh. 15 - The titration curves for two acids with the same...Ch. 15 - Explain why it is that the weaker the acid being...Ch. 15 - Prob. 34QRTCh. 15 - Consider all acid-base indicators discussed in...Ch. 15 - Which of the acid-base indicators discussed in...Ch. 15 - It required 22.6 mL of 0.0140-M Ba(OH)2 solution...Ch. 15 - It took 12.4 mL of 0.205-M H2SO4 solution to...Ch. 15 - Vitamin C is a monoprotic acid. To analyze a...Ch. 15 - An acid-base titration was used to find the...Ch. 15 - Calculate the volume of 0.150-M HCl required to...Ch. 15 - Calculate the volume of 0.225-M NaOH required to...Ch. 15 - Prob. 43QRTCh. 15 - Prob. 44QRTCh. 15 - Prob. 45QRTCh. 15 - Explain why rain with a pH of 6.7 is not...Ch. 15 - Identify two oxides that are key producers of acid...Ch. 15 - Prob. 48QRTCh. 15 - Prob. 49QRTCh. 15 - Prob. 50QRTCh. 15 - Prob. 51QRTCh. 15 - A saturated solution of silver arsenate, Ag3AsO4,...Ch. 15 - Prob. 53QRTCh. 15 - Prob. 54QRTCh. 15 - Prob. 55QRTCh. 15 - Prob. 56QRTCh. 15 - Prob. 57QRTCh. 15 - Prob. 58QRTCh. 15 - Prob. 59QRTCh. 15 - Prob. 60QRTCh. 15 - Prob. 61QRTCh. 15 - Prob. 62QRTCh. 15 - Prob. 63QRTCh. 15 - Prob. 64QRTCh. 15 - Predict what effect each would have on this...Ch. 15 - Prob. 66QRTCh. 15 - Prob. 67QRTCh. 15 - The solubility of Mg(OH)2 in water is...Ch. 15 - Prob. 69QRTCh. 15 - Prob. 70QRTCh. 15 - Prob. 71QRTCh. 15 - Prob. 72QRTCh. 15 - Write the chemical equation for the formation of...Ch. 15 - Prob. 74QRTCh. 15 - Prob. 75QRTCh. 15 - Prob. 76QRTCh. 15 - Prob. 77QRTCh. 15 - Prob. 78QRTCh. 15 - Prob. 79QRTCh. 15 - Prob. 80QRTCh. 15 - Prob. 81QRTCh. 15 - Solid sodium fluoride is slowly added to an...Ch. 15 - Prob. 83QRTCh. 15 - Prob. 84QRTCh. 15 - A buffer solution was prepared by adding 4.95 g...Ch. 15 - Prob. 86QRTCh. 15 - Prob. 87QRTCh. 15 - Prob. 88QRTCh. 15 - Prob. 89QRTCh. 15 - Which of these buffers involving a weak acid HA...Ch. 15 - Prob. 91QRTCh. 15 - Prob. 92QRTCh. 15 - When 40.00 mL of a weak monoprotic acid solution...Ch. 15 - Each of the solutions in the table has the same...Ch. 15 - Prob. 95QRTCh. 15 - Prob. 97QRTCh. 15 - The average normal concentration of Ca2+ in urine...Ch. 15 - Explain why even though an aqueous acetic acid...Ch. 15 - Prob. 100QRTCh. 15 - Prob. 101QRTCh. 15 - Prob. 102QRTCh. 15 - Prob. 103QRTCh. 15 - Prob. 104QRTCh. 15 - Apatite, Ca5(PO4)3OH, is the mineral in teeth.
On...Ch. 15 - Calculate the maximum concentration of Mg2+...Ch. 15 - Prob. 107QRTCh. 15 - Prob. 108QRTCh. 15 - The grid has six lettered boxes, each of which...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Prob. 112QRTCh. 15 - Prob. 113QRTCh. 15 - Prob. 114QRTCh. 15 - Prob. 115QRTCh. 15 - You want to prepare a pH 4.50 buffer using sodium...Ch. 15 - Prob. 117QRTCh. 15 - Prob. 118QRTCh. 15 - Prob. 119QRTCh. 15 - Prob. 120QRTCh. 15 - Prob. 121QRTCh. 15 - Prob. 122QRTCh. 15 - You are given four different aqueous solutions and...Ch. 15 - Prob. 124QRTCh. 15 - Prob. 126QRTCh. 15 - Prob. 15.ACPCh. 15 - Prob. 15.BCP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Ammonia gas is bubbled into 275 mL of water to make an aqueous solution of ammonia. To prepare a buffer with a pH of 9.56, 15.0 g of NH4Cl are added. How many liters of NH3; at 25C and 0.981 atm should be used to prepare the buffer? Assume no volume changes and ignore the vapor pressure of water.arrow_forwardWhat are the [H₃O⁺] and the pH of a buffer that consists of 0.20 M HF and 0.25 M KF (Kₐ of HF =6.8X10⁻⁴)?arrow_forwardTwo solutions are mixed, namely 50 mL 0.2M NaOH and 50 mL 0.1M CH3COOH. Is the decision whether the mixture forms a buffer solution or not? Explain !arrow_forward
- 1a) How many moles of CH₃NH₃Cl need to be added to 200.0 mL of a 0.500 M solution of CH₃NH₂ (Kb for CH₃NH₂ is 4.4 × 10⁻⁴) to make a buffer with a pH of 10.60? 1b) How many moles of NaOH need to be added to 200.0 mL of a 0.200 M solution of HF to make a buffer with a pH of 2.80? (Ka for HF is 6.8 × 10⁻⁴) 1c) What is the pH of a buffer made from 0.350 mol of HBrO (Ka = 2.5 × 10⁻⁹) and 0.070 mol of KBrO in 2.0 L of solution? 1d) What ratio of CH₃NH₂ to CH₃NH₃⁺ is needed to prepare a pH 10.20 buffer? (Kb for CH₃NH₂ is 4.4 × 10⁻⁴)arrow_forwardThere is a 0.100 M solution of CH3CO2H and NaOH.Please explain in detail whether a buffer is formed when 30.00 mL of acetic acid and 20.00 mL of NaOH are combined?arrow_forward1. Choose a suitable acid-base pair to prepare a buffer with a pH of 4.75. 2. You were asked to prepare a 500-mL acetate buffer with a pH of 5.00. Solutions of acetic acid and sodium acetate of equimolar concentrations (same molarity) are available. How many mL of base is needed to prepare this buffer?arrow_forward
- Buffer capacity is a measure of a buffer solution's resistance to changes in pH as strong acid or base is added. Suppose that you have 175 mL of a buffer that is 0.460 M in both propanoic acid (C,H,COOH) and its conjugate base (C,H,CO0-). Calculate the maximum volume of 0.380 M HCl that can be added to the buffer before its buffering capacity is lost.arrow_forwardPlease dont give hand written solutionarrow_forwardConsider a 1.0 L buffer containing 0.11 mol L-1 HF and 0.11 mol L-1 F-. What is the pH of the solution after adding 5.3 x 10-3 mol of NaOH? Please express the answer in two decimal places.arrow_forward
- One Liter of buffer at pH of 4.30 contains 0.33 M of sodium benzoate and 0.26 M of benzoic acid. What is the proton concentration in the solution after the addition of 0.058 mol of HCl (assume the volume does not change)?arrow_forwardA buffer is made up of 0.3 L each of a 0.5 M KH2PO4 and 0.317 M K2HPO4. assuming that volumes are additives calculate a) the pH of the buffer b) the pH of the buffer after the addition of 0.0500mol of HCl to 0.600 L of buffer c) the pH of the buffer after the addition of 0.5 mol of NaOH to 0.600 L of bufferarrow_forwardHow many grams of dry NH4Cl need to be added to 2.50 L of a 0.300 M solution of ammonia, NH3 , to prepare a buffer solution that has a pH of 8.74? Kb for ammonia is 1.8×10−5 . (Please type answer no write by hend)arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY