FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
15th Edition
ISBN: 9781119797807
Author: Hein
Publisher: WILEY
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Chapter 15, Problem 3RQ
Interpretation Introduction

Interpretation:

Equations of neutralization of each of Arrhenius, Bronsted-Lowry and Lewis acid-bass have to be written.

Concept Introduction:

Arrhenius gave the broader picture and suggested that acids can release an excess of H3O+ ion on dissolution in the water while bases can release an excess of OH ion on dissolution in water.

Bronsted-Lowry acid outlined the definition of acids that donate H+ or a proton while bases that accept H+ or a proton.

In accordance with Lewis concept, an acid species accepts an electron-pair from some other electron-rich species while a base that has generally more electron density donates it to another electron-deficient species.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 15 Solutions

FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA

Ch. 15 - Prob. 3RQCh. 15 - Prob. 4RQCh. 15 - Prob. 5RQCh. 15 - Prob. 6RQCh. 15 - Prob. 7RQCh. 15 - Prob. 8RQCh. 15 - Prob. 9RQCh. 15 - Prob. 10RQCh. 15 - Prob. 11RQCh. 15 - Prob. 12RQCh. 15 - Prob. 13RQCh. 15 - Prob. 14RQCh. 15 - Prob. 15RQCh. 15 - Prob. 16RQCh. 15 - Prob. 17RQCh. 15 - Prob. 18RQCh. 15 - Prob. 19RQCh. 15 - Prob. 20RQCh. 15 - Prob. 21RQCh. 15 - Prob. 22RQCh. 15 - Prob. 23RQCh. 15 - Prob. 24RQCh. 15 - Prob. 25RQCh. 15 - Prob. 26RQCh. 15 - Prob. 27RQCh. 15 - Prob. 28RQCh. 15 - Prob. 1PECh. 15 - Prob. 2PECh. 15 - Prob. 3PECh. 15 - Prob. 4PECh. 15 - Prob. 5PECh. 15 - Prob. 6PECh. 15 - Prob. 7PECh. 15 - Prob. 8PECh. 15 - Prob. 9PECh. 15 - Prob. 10PECh. 15 - Prob. 11PECh. 15 - Prob. 12PECh. 15 - Prob. 13PECh. 15 - Prob. 14PECh. 15 - Prob. 15PECh. 15 - Prob. 16PECh. 15 - Prob. 17PECh. 15 - Prob. 18PECh. 15 - Prob. 19PECh. 15 - Prob. 20PECh. 15 - Prob. 21PECh. 15 - Prob. 22PECh. 15 - Prob. 23PECh. 15 - Prob. 24PECh. 15 - Prob. 25PECh. 15 - Prob. 26PECh. 15 - Prob. 27PECh. 15 - Prob. 28PECh. 15 - Prob. 29PECh. 15 - Prob. 30PECh. 15 - Prob. 31PECh. 15 - Prob. 32PECh. 15 - Prob. 33PECh. 15 - Prob. 34PECh. 15 - Prob. 35PECh. 15 - Prob. 36PECh. 15 - Prob. 37PECh. 15 - Prob. 38PECh. 15 - Prob. 39PECh. 15 - Prob. 40PECh. 15 - Prob. 41PECh. 15 - Prob. 42PECh. 15 - Prob. 43PECh. 15 - Prob. 44PECh. 15 - Prob. 45AECh. 15 - Prob. 46AECh. 15 - Prob. 47AECh. 15 - Prob. 48AECh. 15 - Prob. 49AECh. 15 - Prob. 50AECh. 15 - Prob. 51AECh. 15 - Prob. 52AECh. 15 - Prob. 53AECh. 15 - Prob. 54AECh. 15 - Prob. 55AECh. 15 - Prob. 56AECh. 15 - Prob. 57AECh. 15 - Prob. 58AECh. 15 - Prob. 59AECh. 15 - Prob. 60AECh. 15 - Prob. 61AECh. 15 - Prob. 62AECh. 15 - Prob. 63AECh. 15 - Prob. 64AECh. 15 - Prob. 65AECh. 15 - Prob. 66AECh. 15 - Prob. 67AECh. 15 - Prob. 68AECh. 15 - Prob. 69AECh. 15 - Prob. 70AECh. 15 - Prob. 71AECh. 15 - Prob. 72AECh. 15 - Prob. 73CECh. 15 - Prob. 74CE
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